N,N,N-Tributyl-1-butanaminium azide

N,N,N-Tributyl-1-butanaminium azide Structure
N,N,N-Tributyl-1-butanaminium azide structure
Common Name N,N,N-Tributyl-1-butanaminium azide
CAS Number 993-22-6 Molecular Weight 284.484
Density N/A Boiling Point N/A
Molecular Formula C16H36N4 Melting Point 84-88ºC
MSDS Chinese USA Flash Point N/A
Symbol GHS06 GHS09
GHS06, GHS09
Signal Word Danger

High-turnover hypoiodite catalysis for asymmetric synthesis of tocopherols.

Science 345(6194) , 291-4, (2014)

The diverse biological activities of tocopherols and their analogs have inspired considerable interest in the development of routes for their efficient asymmetric synthesis. Here, we report that chiral ammonium hypoiodite salts catalyze highly chemo- and enan...

Tandem cyclization of α-cyano α-alkynyl aryl ketones induced by tert-butyl hydroperoxide and tetrabutylammonium iodide.

Org. Lett. 14(23) , 6024-7, (2012)

The radical cascade protocol of the α-cyano α-TMS/aryl-capped alkynyl aryl ketones promoted by tert-butyl hydroperoxide under catalysis with tetrabutylammonium iodide in refluxing benzene has been developed, leading to the construction of a variety of highly ...

RNA editing in eag potassium channels: biophysical consequences of editing a conserved S6 residue.

Channels (Austin.) 6(6) , 443-52, (2012)

RNA editing at four sites in eag, a Drosophila voltage-gated potassium channel, results in the substitution of amino acids into the final protein product that are not encoded by the genome. These sites and the editing alterations introduced are K467R (Site 1,...

Quantitative imaging of ion transport through single nanopores by high-resolution scanning electrochemical microscopy.

J. Am. Chem. Soc. 134(24) , 9856-9, (2012)

Here we report on the unprecedentedly high resolution imaging of ion transport through single nanopores by scanning electrochemical microscopy (SECM). The quantitative SECM image of single nanopores allows for the determination of their structural properties,...

Photoinduced ligand exchange and DNA binding of cis-[Ru(phpy)(phen)(CH3CN)2]+ with long wavelength visible light.

J. Inorg. Biochem. 121 , 77-87, (2013)

The complex cis-[Ru(phpy)(phen)(CH3CN)2](+) (phpy=2-phenylpyridine, phen=1,10-phenanthroline) was investigated as a potential photodynamic therapy (PDT) agent. This complex presents desirable photochemical characteristics including a low energy absorption tai...

Thermal-induced dynamic self-assembly of adenine-grafted polyoxometalate complexes.

Dalton Trans. 41(33) , 10043-51, (2012)

A new kind of organic-inorganic hybrid complexes based on polyoxometalate were synthesized through symmetrically grafting two adeninyl groups onto Anderson-type MnMo(6) clusters and encapsulating the clusters by organic surfactants. The resultant complexes ex...

Development of a new and environment friendly hollow fiber-supported liquid phase microextraction using vesicular aggregate-based supramolecular solvent.

Analyst 137(15) , 3549-57, (2012)

Hollow fiber-based liquid phase microextraction (HF-LPME) using conventional solvents is limited by their relative instability and high volatility. The use of supramolecular solvents as a liquid membrane phase could overcome these inconveniences due to their ...

Monitoring of thiopurine metabolites - a high-performance liquid chromatography method for clinical use.

J. Pharm. Biomed. Anal. 75 , 145-52, (2013)

A high-performance liquid chromatography method capable of measuring thiopurine mono-, di-, and triphosphates separately in red blood cells (RBCs) was developed. RBCs were isolated from whole blood using centrifugation. Proteins were precipitated using dichlo...

Extraction and stability of pesticide multiresidues from natural water on a mixed-mode admicellar sorbent.

J. Chromatogr. A. 1248 , 74-83, (2012)

The suitability of a mixed-mode sorbent made up of admicelles of sodium dodecyl sulphate (SDS) and tetrabutylammonium (TBA) to extract and preserve pesticides from river and underground water was assessed. Pesticides belonging to different structural groups (...

Gelation via ion exchange in discotic suspensions.

Phys. Rev. Lett. 108(24) , 247802, (2012)

The phase behavior of charged disk suspensions displays a strong dependence on ionic strengths, as the interplay between excluded volume and electrostatic interactions determines the formation of glasses, gels, and liquid crystal states. The various ions in n...