Ethyl cyanoacetate
Ethyl cyanoacetate structure
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Common Name | Ethyl cyanoacetate | ||
|---|---|---|---|---|
| CAS Number | 105-56-6 | Molecular Weight | 113.115 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 203.6±8.0 °C at 760 mmHg | |
| Molecular Formula | C5H7NO2 | Melting Point | -22 °C | |
| MSDS | Chinese USA | Flash Point | 110 ºC | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Self-assembled hybrid metal oxide base catalysts prepared by simply mixing with organic modifiers.
Nat. Commun. 6 , 8580, (2015) Multidentate materials formed by simply mixing heterogeneous and homogeneous components are promising for construction of versatile active sites on the surface of heterogeneous compounds, however, to the best of our knowledge, there are no reports on such mat... |
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Intramolecular Hydrogen Bonding and Linear Pentapyrrole Conformation.
Monatsh. Chem 145(7) , 1117-1135, (2014) Three new linear pentapyrrole rubinoid analogs: 2,3,7,8,17,18,22,23-octamethyl-12,13-bis-(2-carboxyethyl)-1,10,15,24,25,27,28,29-octahydro-27H-pentapyrrin-1,24-dione and 2,3,8,12,13,17,22,23-octamethyl-7,18-bis-(2-carboxyethyl)-1,10,15,24,25,26,27,28,29-octah... |
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Microwave-assisted and efficient solvent-free knoevenagel condensation. A sustainable protocol using porous calcium hydroxyapatite as catalyst.
Molecules 15(2) , 813-23, (2010) A sustainable Knoevenagel condensation of a series of aldehydes with malononitrile and ethyl cyanoacetate is described. The process is based on the combination of microwave activation and hydroxyapatite catalysis under solvent-free conditions. Products are ob... |
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Convenient synthesis of polyfunctional dihydrothiophenes with tandem reaction of 1,3-thiazolidinedione, aldehyde, arylamine and ethyl cyanoacetate.
Mol. Divers. 15(1) , 115-23, (2011) New, highly-functionalized dihydrothiophenes are conveniently synthesized from the novel tandem, four-component reactions of 1,3-thiazolidinedione, aldehyde, arylamine, and ethyl cyanoacetate, catalyzed by triethylamine. The reaction mechanism involves the us... |
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Synthesis of indan-based unusual alpha-amino acid derivatives under phase-transfer catalysis conditions.
J. Org. Chem. 65(5) , 1359-65, (2000) Conformationally constrained cyclic alpha-amino acid derivatives were synthesized under solid-liquid phase-transfer catalysis conditions. This methodology involves the bis-alkylation of ethyl isocyanoacetate with various alpha,alpha'-dibromo-o-xylene derivati... |
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Direct organocatalytic and highly enantio- and diastereoselective Mannich reactions of alpha-substituted alpha-cyanoacetates.
Angew. Chem. Int. Ed. Engl. 44(19) , 2896-9, (2005)
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ATR-IR spectroscopy of pendant NH2 groups on silica involved in the Knoevenagel condensation.
Langmuir 22(8) , 3698-706, (2006) The liquid-phase Knoevenagel condensation between benzaldehyde and ethyl cyanoacetate catalyzed by aminopropyl-modified silica has been investigated using in situ attenuated total reflection infrared (ATR-IR) spectroscopy. The aim of the work was to demonstra... |
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[Information from the Soviet Toxicology Center].
Farmakol. Toksikol. 43(6) , 750-1, (1980)
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Synthesis of 1-(2-naphthylsulfonyl)pyrazole-C-glycosides.
Nucleosides Nucleotides Nucleic Acids 21(6-7) , 469-75, (2002) 2-Naphthylsulfonylhydrazine was reacted with aromatic aldehydes or aldehydo sugars to give the corresponding hydrazones which undergo Michael addition reactions with malononitrile or ethyl cyanoacetate to form pyrazole derivatives. |
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Palladium-catalyzed arylation of ethyl cyanoacetate. Fluorescence resonance energy transfer as a tool for reaction discovery.
J. Am. Chem. Soc. 123(19) , 4641-2, (2001)
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