tert-Butyl peroxybenzoate

tert-Butyl peroxybenzoate Structure
tert-Butyl peroxybenzoate structure
Common Name tert-Butyl peroxybenzoate
CAS Number 614-45-9 Molecular Weight 194.227
Density 1.1±0.1 g/cm3 Boiling Point 282.4±9.0 °C at 760 mmHg
Molecular Formula C11H14O3 Melting Point 8 °C
MSDS Chinese USA Flash Point 109.7±12.8 °C
Symbol GHS02 GHS07 GHS09
GHS02, GHS07, GHS09
Signal Word Danger

Evidence for the metabolism of tumor promoter organic hydroperoxides into free radicals by human carcinoma skin keratinocytes: an ESR-spin trapping study.

Carcinogenesis 10(8) , 1499-503, (1989)

Humans are exposed to various peroxy and hydroperoxy compounds which are in use in the cosmetic, pharmaceutical and polymer industries and which are also generated as a result of the peroxidative metabolic conversion of certain lipids. This study was designed...

Exposure of mouse skin to organic peroxides: subchronic effects related to carcinogenic potential.

Carcinogenesis 25(3) , 431-7, (2004)

Screening of newly synthesized organic peroxides for tumor initiating/promoting activity would be greatly facilitated if predictive methodologies could be developed using topical exposures shorter than those required for definitive tumor assessment in mouse s...

tert-Butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane: efficient synthesis of 6-alkyl phenanthridines via C(sp3)-H/C(sp2)-H bond functionalization.

Chem. Commun. (Camb.) 50(49) , 6439-42, (2014)

An efficient method for the construction of 6-alkyl phenanthridines by tert-butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane was established. Two new C-C bonds were formed in this reaction via a sequential C(sp(3))-H/C(sp(2))-H...

Conformal polymeric thin films by low-temperature rapid initiated chemical vapor deposition (iCVD) using tert-butyl peroxybenzoate as an initiator.

ACS Appl. Mater. Interfaces 3(7) , 2410-6, (2011)

Conformal poly(cyclohexyl methacrylate) (pCHMA) thin films were synthesized via initiated chemical vapor deposition (iCVD), with tert-butyl peroxybenzoate (TBPOB) as the initiator, representing the first time that TBPOB has been used as an initiator for iCVD ...

Chem. Eng. News 59 , 19, (1981)

Structural comparison of products from peroxide-initiated grafting of vinylsilane and silane-functionalized nitroxyl to hydrocarbon and polyolefin substrates. Weaver JD, et al.

J. Polym. Sci. A Polym. Chem. 46(13) , 4542-55, (2008)