2-Amino-3-methylbutan-1-ol
2-Amino-3-methylbutan-1-ol structure
|
Common Name | 2-Amino-3-methylbutan-1-ol | ||
|---|---|---|---|---|
| CAS Number | 16369-05-4 | Molecular Weight | 103.163 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 186.8±13.0 °C at 760 mmHg | |
| Molecular Formula | C5H13NO | Melting Point | 31-32℃ | |
| MSDS | Chinese USA | Flash Point | 91.1±0.0 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
|
Chiral bis(amino alcohol)oxalamide gelators-gelation properties and supramolecular organization: racemate versus pure enantiomer gelation.
Chemistry 9(22) , 5567-80, (2003) Four new chiral bis(amino alcohol)oxalamides (1-4: amino alcohol=leucinol, valinol, phenylglycinol, and phenylalaninol, respectively) have been prepared as low-molecular-weight organic gelators. Their gelation properties towards various organic solvents and m... |
|
|
Synthesis of highly enantioenriched chiral alpha-aminoorganotins via diastereoselective ring opening of chiral N-(arenesulfonyl) 2-tributylstannyloxazolidines.
J. Org. Chem. 74(16) , 5822-38, (2009) trans-N-(Arenesulfonyl)-2-tributylstannyloxazolidines derived from (R)-phenylglycinol were diastereoselectively ring-opened by soft organometallic reagents in the presence of BF(3).OEt(2). Both higher order organocuprates and allyltributyltin afforded the des... |
|
|
General synthesis route to benanomicin-pradimicin antibiotics.
Chemistry 13(35) , 9791-823, (2007) A general approach to the regio- and stereoselective total synthesis of the benanomicin-pradimicin antibiotics (BpAs) is described. Construction of the aglycon has been achieved by 1) the diastereoselective ring-opening of a biaryl lactone by using (R)-valino... |
|
|
Asymmetric synthesis of 8-aminoindolizidine from chiral 2-pyrroleimines.
J. Org. Chem. 73(21) , 8376-81, (2008) 1-Allyl-2-pyrroleimines obtained from (S)-valinol and (S)-phenylglycinol underwent highly diastereoselective addition of allylmagnesium chloride, used in excess amounts, to give the corresponding secondary amines with concomitant allyl to (Z)-1-propenyl isome... |
|
|
Order of binding of substrate to valyl-tRNA synthetase from Bacillus stearothermophilus in amino acid activation reaction.
Biochem. Int. 14(4) , 597-603, (1987) Amino acid activation reaction with valyl-tRNA synthetase (EC 6.1.1.9) from Bacillus stearothermophilus was studied kinetically by measuring ATP-PPi exchange to find the order of the binding of substrate to the enzyme. The effects of the concentration of the ... |
|
|
Dietary low-dose sucrose modulation of IQ-induced genotoxicity in the colon and liver of Big Blue rats.
Mutat. Res. 527(1-2) , 91-7, (2003) Earlier studies have indicated that sucrose increases 2-amino-3-methylimidazo[4,5-f]quinoline (IQ)-induced aberrant crypt foci in the colon. In this study, we investigated the role of sucrose in IQ-induced genotoxicity of the colon mucosa and liver. Big Blue ... |
|
|
Highly enantioselective borane reduction of heteroaryl and heterocyclic ketoxime ethers catalyzed by novel spiroborate ester derived from diphenylvalinol: application to the synthesis of nicotine analogues.
J. Org. Chem. 73(11) , 4017-26, (2008) An asymmetric synthesis for the preparation of nonracemic amines bearing heterocyclic and heteroaromatic rings is described. A variety of important enantiopure thionyl and arylalkyl primary amines were afforded by the borane-mediated enantioselective reductio... |
|
|
A long-range chiral relay via tertiary amide group in asymmetric catalysis: new amino acid-derived N,P-ligands for copper-catalysed conjugate addition.
Chem. Commun. (Camb.) (15) , 1948-9, (2003) New N,P-ligands 4-6, derived from valinol and prolinol, respectively, have been developed for the asymmetric, copper(I)-catalysed conjugate addition of diethylzinc to unsaturated ketones; the tertiary amide group has been shown to effectively relay the chiral... |
|
|
EGF receptors on plasma membranes purified from bovine mammary gland of lactating and pregnant animals.
Biochem. Int. 14(4) , 581-8, (1987) A procedure for purification of plasma membranes from bovine mammary gland has been developed. The binding capacity of EGF to the plasma membranes from mammary tissue of pregnant cows was equal to 335 fmol per mg of protein thus being twofold higher than in m... |
|
|
Invariom-model refinement of L-valinol.
Acta Crystallogr. C 62(Pt 11) , o633-5, (2006) The structure of L-valinol [(S)-(+)-2-amino-3-methylbutan-1-ol or hydroxylated L-valine], C5H13NO, has been determined at 100 K by single-crystal X-ray diffraction. The independent atom model geometry, Flack parameter and figures of merit are compared with re... |