Sodium tetraphenylborate

Sodium tetraphenylborate Structure
Sodium tetraphenylborate structure
Common Name Sodium tetraphenylborate
CAS Number 143-66-8 Molecular Weight 342.216
Density 1.15 g/cm3 Boiling Point N/A
Molecular Formula C24H20BNa Melting Point 300 °C
MSDS Chinese USA Flash Point N/A
Symbol GHS06
GHS06
Signal Word Danger

Synthesis, characterization, photophysics and electrochemical study of luminescent iridium(III) complexes with isocyanoborate ligands.

Dalton Trans. 44 , 15135-44, (2015)

A new series of cyclometalated iridium(III) complexes with isocyanoborate ligands [Ir(R2ppy)2(L)(CNBR'3)] (R = H or F; L = CNC6H4Cl-4 or PPh3; R' = Ph, C6F5 or C6H4Cl-4), [Ir(biqb)(ppy)(CNBR''3)] (R'' = C6F5 or C6H4Cl-4) and {Ir(ppy)2(CN)n[CNB(C6F5)3]2-n}(-) ...

Anions make the difference: insights from the interaction of big cations and anions with poly(N-isopropylacrylamide) chains and microgels.

Soft Matter 11 , 5077-86, (2015)

Minute concentrations of big hydrophobic ions have the ability to induce substantial effects in soft matter systems, including novel phases in lipid layers, giant charge inversion in colloids and nanostructuration in polymer surfaces in contact with water. Th...

Effect of Chaenomeles sinensis Extract on Choline Acetyltransferase Activity and Trimethyltin-Induced Learning and Memory Impairment in Mice.

Chem. Pharm. Bull. 63 , 1076-80, (2015)

The aim of this study was to search for a novel choline acetyltransferase (ChAT) activator from plants traditionally grown in Korea. An ethanol extract from Chaenomeles sinensis Koehne showed the highest ChAT-activating effect in vitro in an assay that used h...

Hippocampal Lewy pathology and cholinergic dysfunction are associated with dementia in Parkinson's disease.

Brain 137(Pt 9) , 2493-508, (2014)

The neuropathological substrate of dementia in patients with Parkinson's disease is still under debate, particularly in patients with insufficient alternate neuropathology for other degenerative dementias. In patients with pure Lewy body Parkinson's disease, ...

Membrane sensors for the selective determination of donepezil hydrochloride.

J. AOAC Int. 93(2) , 549-55, (2010)

The construction and electrochemical response characteristics of polyvinylchloride (PVC) membrane sensors for donepezil HCl (DP) are described. The sensing membranes incorporated ion-association complexes of DP cation and sodium tetraphenyl borate (sensor 1),...

An efficient and selective flourescent chemical sensor based on 5-(8-hydroxy-2-quinolinylmethyl)-2,8-dithia-5-aza-2,6-pyridinophane as a new fluoroionophore for determination of iron(III) ions. A novel probe for iron speciation.

Anal. Chim. Acta 761 , 169-77, (2013)

A novel fluorescent chemical sensor for the highly sensitive and selective determination of Fe(3+) ions in aqueous solutions is prepared. The iron sensing system was prepared by incorporating 5-(8-hydroxy-2-quinolinylmethyl)-2,8-dithia-5-aza-2,6-pyridinophane...

Halogen-free ionic liquid as an additive in zinc(II)-selective electrode: surface analyses as correlated to the membrane activity.

Talanta 94 , 184-8, (2012)

Two conventional Zn(II) polyvinyl chloride (PVC) membrane electrodes have been prepared and characterized. They were based on dibenzo-24-crown-8 (DBC) as a neutral carrier, dioctyl phthalate (DOP) as a plasticizer, and potassium tetrakis (p-chlorophenyl) bora...

Interfacial complexes between a protein and lipophilic ions at an oil-water interface.

Anal. Chem. 82(18) , 7699-705, (2010)

The interaction between an intact protein and two lipophilic ions at an oil-water interface has been investigated using cyclic voltammetry, impedance based techniques and a newly developed method in which the biphasic oil-water system is analyzed by biphasic ...

A multinuclear solid-state NMR study of alkali metal ions in tetraphenylborate salts, M[BPh4] (M = Na, K, Rb and Cs): what is the NMR signature of cation-pi interactions?

J. Phys. Chem. A 112(41) , 10359-64, (2008)

We report a multinuclear solid-state ( (23)Na, (39)K, (87)Rb, (133)Cs) NMR study of tetraphenylborate salts, M[BPh 4] (M = Na, K, Rb, Cs). These compounds are isostructural in the solid state with the alkali metal ion surrounded by four phenyl groups resultin...

Comparison of tetraethylborate and tetraphenylborate for selenite determination in human urine by gas chromatography mass spectrometry, after headspace solid phase microextraction.

Talanta 80(3) , 1311-7, (2010)

Two different derivatizing reagents were tested for the development of a fast and sensitive method for the determination of selenites (Se(IV)) in human urine. The reagents were sodium tetraethylborate (NaBEt(4)) and tetraphenylborate (NaBPh(4)), respectively,...