Sodium imidazolide
Sodium imidazolide structure
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Common Name | Sodium imidazolide | ||
|---|---|---|---|---|
| CAS Number | 5587-42-8 | Molecular Weight | 90.05910 | |
| Density | 1.116g/cm3 | Boiling Point | 257ºC at 760mmHg | |
| Molecular Formula | C3H3N2Na | Melting Point | 284ºC (dec.)(lit.) | |
| MSDS | Chinese USA | Flash Point | 145ºC | |
| Symbol |
GHS05, GHS07 |
Signal Word | Danger | |
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Identification of a pKa-regulating motif stabilizing imidazole-modified double-stranded DNA.
Nucleic Acids Res. 43(1) , 51-62, (2015) The predictable 3D structure of double-stranded DNA renders it ideally suited as a template for the bottom-up design of functionalized nucleic acid-based active sites. We here explore the use of a 14mer DNA duplex as a scaffold for the precise and predictable... |
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Organic-inorganic hybrids of imidazole complexes of zinc (II) for catalysts in the glycerolysis of urea.
J. Nanosci. Nanotechnol. 14(6) , 4632-8, (2014) Bis(alkylimidazole) complexes of zinc, (RIm)2ZnX2, were prepared by a metal insertion reaction. The synthesized (RIm)2ZnX2 exhibited good catalytic performance during synthesis of glycerol carbonate (GC) from glycerol and urea. (HEIm)2ZnCl2 with a hydroxyl gr... |
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Fluorogenic dansyl-ligated gold nanoparticles for the detection of sulfur mustard by displacement assay.
Chem. Commun. (Camb.) 49(23) , 2293-5, (2013) The dansyl fluorophore ligated to gold nanoparticles via imidazole and amine groups affords conjugates capable of detecting micromolar concentrations of the chemical warfare agent sulfur mustard by a fluorescence switching 'ON' displacement assay. |
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Electrocatalytic O2 reduction reaction by synthetic analogues of cytochrome P450 and myoglobin: in-situ resonance Raman and dynamic electrochemistry investigations.
Inorg. Chem. 52(17) , 9897-907, (2013) Bioinspired electrodes have been constructed by physiabsorption of two air stable iron porphyrin complexes, one bearing an imidazole coordination and the other bearing a thiolate coordination. To control the electron transfer (ET) rate to these O2 reducing el... |
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Animal toxicity of hairpin pyrrole-imidazole polyamides varies with the turn unit.
J. Med. Chem. 56(18) , 7449-57, (2013) A hairpin pyrrole-imidazole polyamide (1) targeted to the androgen receptor consensus half-site was found to exert antitumor effects against prostate cancer xenografts. A previous animal study showed that 1, which has a chiral amine at the α-position of the γ... |
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Noncovalent interactions in halogenated ionic liquids: theoretical study and crystallographic implications.
Phys. Chem. Chem. Phys. 15(12) , 4405-14, (2013) In recent years, several specific imidazolium-based ionic liquids with halogen substituents on the imidazole ring as well as on the alkyl chains have been reported. In this work, noncovalent interactions in four halogenated ionic liquids, i.e. 2-bromo-/iodo- ... |
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Chiral profiling of azole antifungals in municipal wastewater and recipient rivers of the Pearl River Delta, China.
Environ. Sci. Pollut. Res. Int. 20(12) , 8890-9, (2013) Enantiomeric compositions and fractions (EFs) of three chiral imidazole (econazole, ketoconazole, and miconazole) and one chiral triazole (tebuconazole) antifungals were investigated in wastewater, river water, and bed sediment of the Pearl River Delta, South... |
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Transducer influence of polycyclic aromatic hydrocarbons (PAHs) on photoisomerisation of 1-alkyl-2-(arylazo)imidazoles.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 104 , 477-85, (2013) The UV light irradiation to a solution of 1-alkyl-2-(arylazo)imidazole (L) in toluene shows transformation of trans to cis configuration about -N=N- bond. The rate of photo-isomerisation and quantum yields are influenced by internal parameters like - nature o... |
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Potent BRAF kinase inhibitors based on 2,4,5-trisubstituted imidazole with naphthyl and benzothiophene 4-substituents.
Bioorg. Med. Chem. 21(5) , 1284-304, (2013) The RAS-RAF-MEK-ERK pathway is hyperactivated in 30% of human cancers. BRAF is a serine-threonine kinase, belonging to this pathway that is mutated with high frequency in human melanoma and other cancers thus BRAF is an important therapeutic target in melanom... |
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Selective inhibition of glycosyltransferases by bivalent imidazolium salts.
Bioorg. Med. Chem. 21(5) , 1305-11, (2013) Galactosyltransferases (GalTs) extend the glycan chains of mammalian glycoproteins by adding Gal to terminal GlcNAc residues, and thus build the scaffolds for biologically important glycan structures. We have shown that positively charged bivalent imidazolium... |