benzylsulfide
benzylsulfide structure
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Common Name | benzylsulfide | ||
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| CAS Number | 538-74-9 | Molecular Weight | 214.326 | |
| Density | 1.1±0.1 g/cm3 | Boiling Point | 322.8±11.0 °C at 760 mmHg | |
| Molecular Formula | C14H14S | Melting Point | 44-47 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 142.5±15.9 °C | |
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Singlet oxygen promoted carbon-heteroatom bond cleavage in dibenzyl sulfides and tertiary dibenzylamines. Structural effects and the role of exciplexes.
J. Org. Chem. 72(25) , 9582-9, (2007) The C-heteroatom cleavage reactions of substituted dibenzyl sulfides and substituted dibenzylcyclohexylamines promoted by singlet oxygen in MeCN have been investigated. In both systems, the cleavage reactions (leading to benzaldehyde and substituted benzaldeh... |
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Functional groups and sulfur K-edge XANES spectra: divalent sulfur and disulfides.
J. Phys. Chem. A 114(35) , 9523-8, (2010) Sulfur K-edge XANES was measured for two divalent sulfurs (dibenzyl and benzyl phenyl) and two disulfides (dibenzyl and diphenyl). The absorption spectra could be assigned using density functional theory with the "half core hole" approximation for the core ho... |
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Dibenzyl sulfide metabolism by white rot fungi.
Appl. Environ. Microbiol. 69(2) , 1320-4, (2003) Microbial metabolism of organosulfur compounds is of interest in the petroleum industry for in-field viscosity reduction and desulfurization. Here, dibenzyl sulfide (DBS) metabolism in white rot fungi was studied. Trametes trogii UAMH 8156, Trametes hirsuta U... |
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[Diffusional system for examination of the solubility and penetration of water-insoluble compounds (author's transl)].
Zentralbl. Bakteriol. Naturwiss. 135(4) , 308-12, (1980) A diffusion cell type which is suitable for investigation of water-insoluble compounds is shown. The chamber consists of two compartments, the so-called bottom-chamber, which contains the solid substance under investigation, and the main chamber, which is abo... |
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A combined theoretical and experimental investigation on the enantioselective oxidation of aryl benzyl sulfides in the presence of a chiral titanium catalyst.
Chemistry 15(48) , 13417-26, (2009) An experimental investigation of the enantioselective oxidation of aryl benzyl sulfides by tert-butyl hydroperoxide in the presence of a titanium/hydrobenzoin catalyst has shown that these sulfides are ideal substrates for this catalytic system, with negligib... |
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Gene overexpression, purification, and identification of a desulfurization enzyme from Rhodococcus sp. strain IGTS8 as a sulfide/sulfoxide monooxygenase.
J. Bacteriol. 178(19) , 5699-705, (1996) The oxidation of dibenzothiophene to dibenzothiophene sulfone has been linked to the enzyme encoded by the sox/dszC gene from Rhodococcus sp. strain IGTS8 (S. A. Denome, C. Oldfield, L. J. Nash, and K. D. Young, J. Bacteriol. 176:6707-6717, 1994; C. S. Piddin... |
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Disassembly of microtubules and inhibition of neurite outgrowth, neuroblastoma cell proliferation, and MAP kinase tyrosine dephosphorylation by dibenzyl trisulphide.
Biochim. Biophys. Acta 1540(2) , 166-77, (2001) Dibenzyl trisulphide (DTS), a main lipophilic compound in Petiveria alliacea L. (Phytolaccaceae), was identified as one of the active immunomodulatory compounds in extracts of the plant. To learn more about its biological activities and molecular mechanisms, ... |
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Fungal cleavage of thioether bond found in Yperite.
FEBS Lett. 412(2) , 281-4, (1997) The degradation of thiodiglycol (I) and benzyl sulfide (II) was attempted using Coriolus versicolor and Tyromyces palustris to investigate the potential ability of basidiomycetes to degrade Yperite (bis(2-chloroethyl) sulfide), a mass-produced and stored chem... |
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Four- and five-membered cobaltacycles by regioselective cyclometallation of benzyl sulfide derivatives via Co(v) intermediates.
Dalton Trans. (37) , 4981-3, (2008) C-H activation through the coordination of a benzyl sulfide anchoring group with a C-S bond cleavage at a Co(v) center constitutes a regiospecific access to four- and five-membered metallacycles under mild conditions. |
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[Oxidative degradation of dibenzylsulfide].
Z. Allg. Mikrobiol. 19(8) , 527-33, (1979) Dibenzylsulfid (DBS) as a model of the organic sulfur compounds in crude oil was converted by a mixed culture (containing Pseudomonas aeruginosa) into several water soluble organic substances. Whereas these compounds are detectable with DC- and IR-spectroscop... |