Dalton Transactions (Print Edition) 2008-10-07

Four- and five-membered cobaltacycles by regioselective cyclometallation of benzyl sulfide derivatives via Co(v) intermediates.

Robert Beck, Markus Frey, Sebnem Camadanli, Hans-Friedrich Klein

Index: Dalton Trans. (37) , 4981-3, (2008)

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Abstract

C-H activation through the coordination of a benzyl sulfide anchoring group with a C-S bond cleavage at a Co(v) center constitutes a regiospecific access to four- and five-membered metallacycles under mild conditions.