METHYL 2,3-ANHYDRO-4,6-O-BENZYLIDENE-α-D-ALLOPYRANOSIDE
METHYL 2,3-ANHYDRO-4,6-O-BENZYLIDENE-α-D-ALLOPYRANOSIDE structure
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Common Name | METHYL 2,3-ANHYDRO-4,6-O-BENZYLIDENE-α-D-ALLOPYRANOSIDE | ||
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| CAS Number | 3150-15-0 | Molecular Weight | 264.27 | |
| Density | 1.32g/cm3 | Boiling Point | 391ºC at 760mmHg | |
| Molecular Formula | C14H16O5 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 165.4ºC | |
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An alternative synthesis of methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside using carbonate esters Raaijmakers, H., et al.
Carbohydr. Res. 238 , 185-92, (1993)
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Neighboring-group participation in benzylidene acetal ring-opening of a 2-cyano-2-deoxypyranoside derivative by diethylaluminum cyanide.
Carbohydr. Res. 338 , 2177-83, (2003) The oxirane ring-opening of an anhydro sugar with diethylaluminum cyanide (Et(2)AlCN) is a direct approach for obtaining a cyano derivative. Methyl 2,3-anhydro-4,6-O-benzylidene-alpha-D-allopyranoside showed anomalous chemical behavior when treated with Et(2)... |
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Reaction of methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside with ethanolamine and 1,4,7,10-tetraoxa-13-azacyclopentadecane Tóth, G., et al.
Carbohydr. Res. 168 , 141-5, (1987)
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