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甲基2,3-脱水-4,6-O-亚苄基-Α-D-吡喃糖苷

甲基2,3-脱水-4,6-O-亚苄基-Α-D-吡喃糖苷结构式
甲基2,3-脱水-4,6-O-亚苄基-Α-D-吡喃糖苷结构式
品牌特惠专场
常用名 甲基2,3-脱水-4,6-O-亚苄基-Α-D-吡喃糖苷 英文名 METHYL 2,3-ANHYDRO-4,6-O-BENZYLIDENE-α-D-ALLOPYRANOSIDE
CAS号 3150-15-0 分子量 264.27
密度 1.32g/cm3 沸点 391ºC at 760mmHg
分子式 C14H16O5 熔点 N/A
MSDS 中文版 美版 闪点 165.4ºC

An alternative synthesis of methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside using carbonate esters Raaijmakers, H., et al.

Carbohydr. Res. 238 , 185-92, (1993)

Neighboring-group participation in benzylidene acetal ring-opening of a 2-cyano-2-deoxypyranoside derivative by diethylaluminum cyanide.

Carbohydr. Res. 338 , 2177-83, (2003)

The oxirane ring-opening of an anhydro sugar with diethylaluminum cyanide (Et(2)AlCN) is a direct approach for obtaining a cyano derivative. Methyl 2,3-anhydro-4,6-O-benzylidene-alpha-D-allopyranoside showed anomalous chemical behavior when treated with Et(2)...

Reaction of methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside with ethanolamine and 1,4,7,10-tetraoxa-13-azacyclopentadecane Tóth, G., et al.

Carbohydr. Res. 168 , 141-5, (1987)