Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate structure
|
Common Name | Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate | ||
|---|---|---|---|---|
| CAS Number | 53317-87-6 | Molecular Weight | 1480.56000 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C54H45Au3BF4OP3 | Melting Point | 207ºC (dec.) | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
|
Gold(I)-catalyzed propargyl Claisen rearrangement.
J. Am. Chem. Soc. 126 , 15978, (2004) Homoallenic alcohols are prepared from propargyl vinyl ethers using a trinuclear gold(I)-oxo complex, [(Ph3PAu)3O]BF4, as a catalyst for propargyl Claisen rearrangement at room temperature. The gold(I)-catalyzed reaction is effective for a diverse collection ... |
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