Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate

Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate Structure
Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate structure
Common Name Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate
CAS Number 53317-87-6 Molecular Weight 1480.56000
Density N/A Boiling Point N/A
Molecular Formula C54H45Au3BF4OP3 Melting Point 207ºC (dec.)
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

Gold(I)-catalyzed propargyl Claisen rearrangement.

J. Am. Chem. Soc. 126 , 15978, (2004)

Homoallenic alcohols are prepared from propargyl vinyl ethers using a trinuclear gold(I)-oxo complex, [(Ph3PAu)3O]BF4, as a catalyst for propargyl Claisen rearrangement at room temperature. The gold(I)-catalyzed reaction is effective for a diverse collection ...