Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate
![Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate Structure](https://image.chemsrc.com/caspic/354/53317-87-6.png)
Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate structure
|
Common Name | Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate | ||
|---|---|---|---|---|
| CAS Number | 53317-87-6 | Molecular Weight | 1480.56000 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C54H45Au3BF4OP3 | Melting Point | 207ºC (dec.) | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | oxidanium,gold,triphenylphosphane,tetrafluoroborate |
|---|---|
| Synonym | More Synonyms |
| Melting Point | 207ºC (dec.) |
|---|---|
| Molecular Formula | C54H45Au3BF4OP3 |
| Molecular Weight | 1480.56000 |
| Exact Mass | 1480.17000 |
| PSA | 50.00000 |
| LogP | 11.55850 |
| InChIKey | TUNHIOLOUADRRZ-UHFFFAOYSA-O |
| SMILES | F[B-](F)(F)F.[Au].[Au].[Au].[OH3+].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1 |
| Storage condition | 2-8°C |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H315-H319-H335 |
| Precautionary Statements | P280-P304 + P340 + P312-P305 + P351 + P338-P337 + P313 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xi |
| Risk Phrases | 36/37/38 |
| Safety Phrases | 26-36/37/39 |
| RIDADR | NONH for all modes of transport |
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Tris[triphenylp... CAS#:53317-87-6 |
| Literature: Grohmann, Andreas; Riede, Juergen; Schmidbaur, Hubert Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1991 , p. 783 - 788 |
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Tris[triphenylp... CAS#:53317-87-6
Detail
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| Literature: Grohmann, Andreas; Riede, Juergen; Schmidbaur, Hubert Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1992 , vol. 47, # 9 p. 1255 - 1260 |
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~14%
Tris[triphenylp... CAS#:53317-87-6 |
| Literature: Banditelli, Guido; Bandini, Anna Laura; Bonati, Flavio; Goel, Ram G.; Minghetti, Giovanni Gazzetta Chimica Italiana, 1982 , vol. 112, p. 539 - 542 |
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Tris[triphenylp... CAS#:53317-87-6 |
| Literature: Cinellu, Maria Agostina; Stoccoru, Sergio; Minghetti, Giovanni; Bandini, Anna Laura; Demartin, Francesco Inorganica Chimica Acta, 1990 , vol. 168, p. 33 - 42 |
![(7-nitro-2-oxo-5-phenyl-2,3-dihydro-1H-benzo[e][1,4]diazepin-1-yl)(triphenyl-5-phosphanyl)gold structure](https://image.chemsrc.com/caspic/423/128493-73-2.png)
CAS#:24228-71-5![[dichloro(cyano)methyl]-triphenylphosphanium,gold structure](https://image.chemsrc.com/caspic/173/90142-79-3.png)
CAS#:90142-79-3|
Gold(I)-catalyzed propargyl Claisen rearrangement.
J. Am. Chem. Soc. 126 , 15978, (2004) Homoallenic alcohols are prepared from propargyl vinyl ethers using a trinuclear gold(I)-oxo complex, [(Ph3PAu)3O]BF4, as a catalyst for propargyl Claisen rearrangement at room temperature. The gold(I... |
| tris[(triphenylphosphane)gold(I)]oxonium tetrafluoroborate |
| tris[(triphenylphosphino)aurio(I)]oxonium tetrafluoroborate |
| MFCD06658141 |
| [(PPh3Au)3O]BF4 |
| [(Ph3PAu)3O]BF4 |
| TRIS[TRIPHENYLPHOSPHINEGOLD(I)]OXONIUM TETRAFLUOROBORATE |
| Oxotris(triphenylphosphine)trigold tetrafluoroborate |
| Oxotris((triphenylphosphine)gold) tetrafluoroborate |
| [Au(PPh3)O]BF4 |
| {[(triphenylphosphino)Au]3O}BF4 |
| Tris(triphenylphosphinegold)oxonium tetrafluoroborate |