Grubbs Catalyst 2nd Generation
Grubbs Catalyst 2nd Generation structure
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Common Name | Grubbs Catalyst 2nd Generation | ||
|---|---|---|---|---|
| CAS Number | 246047-72-3 | Molecular Weight | 848.971 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C46H65Cl2N2PRu | Melting Point | 143-149ºC | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS02 |
Signal Word | Warning | |
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Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts.
Chem. Rev. 110 , 1746, (2010)
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Olefin Metathesis and Beyond A list of abbreviations can be found at the end of this article.
Angew. Chem. Int. Ed. Engl. 39 , 3012, (2000) The advent of well-defined catalysts for olefin metathesis which combine high activity, durability, and excellent tolerance towards polar functional groups has revolutionized the field. The past decade has seen the rapid embrace of these reagents as tools for... |
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Highly Efficient Ring-Opening Metathesis Polymerization (ROMP) Using New Ruthenium Catalysts Containing N-Heterocyclic Carbene Ligands C.B. is grateful to the National Science Foundation for a pre-doctoral fellowship. The authors thank Dr. Matthias Scholl for providing catalysts 4 a and 4 c.
Angew. Chem. Int. Ed. Engl. 39 , 2903, (2000)
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The development of L2X2Ru=CHR olefin metathesis catalysts: an organometallic success story.
Acc. Chem. Res. 34 , 18, (2001) In recent years, the olefin metathesis reaction has attracted widespread attention as a versatile carbon-carbon bond-forming method. Many new applications have become possible because of major advances in catalyst design. State-of-the-art ruthenium catalysts ... |
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Synthesis and activity of a new generation of ruthenium-based olefin metathesis catalysts coordinated with 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ligands.
Org. Lett. 1 , 953, (1999) [formula: see text] A new family of 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene-substituted ruthenium-based complexes 9a-c has been prepared starting from RuCl2(=CHPh)(PCy3)2 2. These air- and water-tolerant complexes were shown to exhibit an increased ring-c... |
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Synthesis of trisubstituted alkenes via olefin cross-metathesis.
Org. Lett. 1 , 1751, (1999) [formula: see text] Trisubstituted alkenes have been prepared for the first time via intermolecular olefin cross-metathesis, using 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ruthenium alkylidene complexes 3a,b in good yields with moderate E selectivity. In a... |
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Expanded scope in ethylene-alkyne cross-metathesis: coordinating heteroatom functionality at the propargylic position.
Org. Lett. 2 , 2271, (2000) The Grubbs 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene-substituted ruthenium complex 1 catalyzed ethylene-alkyne cross-metathesis and was shown to tolerate free hydroxyl groups and coordinating functionality at the propargylic and homopropargylic positions. H... |
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Unusual influence of substituents on ring-opening metathesis reactions.
Org. Lett. 3 , 4275, (2001) The ring-opening cross-metathesis of oxabicyclo[3.2.1]octene derivatives provides a convenient method for preparing differentially substituted 4-pyrones. The major competing reaction is the ring-opening metathesis polymerization of the bridged olefin. Studies... |
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Olefin-metathesis catalysts for the preparation of molecules and materials (Nobel Lecture).
Angew. Chem. Int. Ed. Engl. 45 , 3760, (2006)
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Schrodi, Y.; Pederson, R. L.
Aldrichimica Acta 40th ed.,, 45, (2007)
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