1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, structure
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Common Name | 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, | ||
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| CAS Number | 95408-45-0 | Molecular Weight | 651.746 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C26H44Cl2FeP2Pd | Melting Point | 203-208ºC | |
| MSDS | USA | Flash Point | N/A | |
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Room-temperature Suzuki-Miyaura couplings in water facilitated by nonionic amphiphiles.
Org. Lett. 10 , 1333, (2008) Use of a dilute aqueous solution containing a nonionic amphiphile allows efficient Suzuki-Miyaura cross-couplings of arylboronic acids with a wide array of aryl halides and pseudohalides, including sterically hindered and lipophilic substrates, in most cases ... |
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Cp2Fe(PR2)2PdCl2 (R = i-Pr, t-Bu) complexes as air-stable catalysts for challenging Suzuki coupling reactions.
Org. Lett. 6 , 3731, (2004) [reaction: see text] The use of Cp(2)Fe(PR(2))(2)PdCl(2) (R = i-Pr and t-Bu) in Suzuki coupling reactions were illustrated using a high throughput screening approach. The di-tbpfPdCl(2) catalyst was shown to be the more active catalyst for unactivated and ste... |
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Heck couplings at room temperature in nanometer aqueous micelles.
Org. Lett. 10 , 1329, (2008) A nonionic amphiphile such as Triton X-100 or the vitamin E-based PTS, both of which form nanomicelles in water, promotes Heck cross-couplings of non-water-soluble partners at ambient temperatures. These are the first examples of Heck reactions conducted in w... |
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alpha-arylation of ketones using highly active, air-stable (DtBPF)PdX2 (X = Cl, Br) catalysts.
Org. Lett. 9 , 5489, (2007) alpha-Arylation of various ketones with aryl chlorides and bromides using the well-defined and air-stable (DtBPF)PdX2 (X = Cl, Br) catalysts gave 80-100% yield of the coupled products under relatively mild conditions at low catalyst loadings. The X-ray struct... |
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CRC International Symposium: Cross Coupling and Organometallics. Colacot T.
Platinum Metals Rev. 52(3) , 172, (2008)
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A simple way of recycling of homogeneous catalyst in Suzuki reaction. Manjunatha SG, et al.
Green Chem. Lett. Rev. 6(1) , 77-87, (2013)
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Synthesis and electrochemistry of late transition metal complexes containing 1, 1'-bis (dicyclohexylphosphino) ferrocene (dcpf). The X-ray structure of [PdCl 2 (dcpf)] and Buchwald-Hartwig catalysis using [PdCl2(bisphosphinometallocene)] precursors. Hagopian LE, et al.
J. Organomet. Chem. 691(23) , 4890-4900, (2006)
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The 2010 Nobel Prize in chemistry: palladium-catalysed cross-coupling. Colacot TJ.
Platinum Metals Rev. 55(2) , 84-90, (2011)
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An Effective Activation of Palladium Phosphine Complexes in Aqueous Phase Reactions of Hetero-Aromatic Boronic Acids with Aryl Halides. Bumagin NA, et al.
Chem. Heterocycl. Comp. 50(1) , 19-25, (2011)
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Natural and Synthetic Chalcones: Tools for the Study of Targets of Action-Insulin Secretagogue or Insulin Mimetic? Nunes RJ, et al.
Stud. Nat. Prod. Chem. , (2013) 39 , 62
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