Organic Letters 2008-04-03

Heck couplings at room temperature in nanometer aqueous micelles.

Bruce H Lipshutz, Benjamin R Taft

Index: Org. Lett. 10 , 1329, (2008)

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Abstract

A nonionic amphiphile such as Triton X-100 or the vitamin E-based PTS, both of which form nanomicelles in water, promotes Heck cross-couplings of non-water-soluble partners at ambient temperatures. These are the first examples of Heck reactions conducted in water (as the only solvent) at room temperature.

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Heck couplings at room temperature in nanometer aqueous micelles.

Abstract

Related Compounds