1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene
1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene structure
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Common Name | 1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene | ||
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| CAS Number | 31469-15-5 | Molecular Weight | 174.313 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 137.4±0.0 °C at 760 mmHg | |
| Molecular Formula | C8H18O2Si | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 14.4±0.0 °C | |
| Symbol |
GHS02, GHS07 |
Signal Word | Warning | |
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Chiral Brønsted acid catalyzed enantioselective Mannich-type reaction.
J. Am. Chem. Soc. 129 , 6756, (2007) Mannich-type reaction of ketene silyl acetals with aldimines proceeded catalytically by means of a phosphoric acid diester, derived from (R)-BINOL, as a chiral Brønsted acid to afford beta-amino esters with good diastereoselectivity in favor of the syn isomer... |
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Asymmetric synthesis of ?-lactams. I. The reaction of dimethylketene silyl acetal with (S)-alkylidene (1-arylethyl) amines promoted by titanium tetrachloride.
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