1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene
1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene structure
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Common Name | 1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene | ||
|---|---|---|---|---|
| CAS Number | 31469-15-5 | Molecular Weight | 174.313 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 137.4±0.0 °C at 760 mmHg | |
| Molecular Formula | C8H18O2Si | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 14.4±0.0 °C | |
| Symbol |
GHS02, GHS07 |
Signal Word | Warning | |
| Name | (1-methoxy-2-methylprop-1-enoxy)-trimethylsilane |
|---|---|
| Synonym | More Synonyms |
| Density | 0.9±0.1 g/cm3 |
|---|---|
| Boiling Point | 137.4±0.0 °C at 760 mmHg |
| Molecular Formula | C8H18O2Si |
| Molecular Weight | 174.313 |
| Flash Point | 14.4±0.0 °C |
| Exact Mass | 174.107605 |
| PSA | 18.46000 |
| LogP | 3.27 |
| Vapour Pressure | 8.8±0.2 mmHg at 25°C |
| Index of Refraction | 1.419 |
| Storage condition | 2-8°C |
| Symbol |
GHS02, GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H226-H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi: Irritant; |
| Risk Phrases | R10 |
| Safety Phrases | S16-S26-S36 |
| RIDADR | UN 3271 3/PG 3 |
| WGK Germany | 3 |
| Packaging Group | III |
| Hazard Class | 3 |
| HS Code | 2931900090 |
|
~85%
1-Methoxy-1-(Tr... CAS#:31469-15-5 |
| Literature: Paquette, Leo A.; Parker, Gregory D.; Tei, Takahiro; Dong, Shuzhi Journal of Organic Chemistry, 2007 , vol. 72, # 19 p. 7124 - 7134 |
|
~83%
1-Methoxy-1-(Tr... CAS#:31469-15-5 |
| Literature: Revis, Anthony; Hilty, Terrence K. Journal of Organic Chemistry, 1990 , vol. 55, # 9 p. 2972 - 2973 |
|
~20%
1-Methoxy-1-(Tr... CAS#:31469-15-5 |
| Literature: Oesterle, Thomas; Simchen, Gerhard Liebigs Annalen der Chemie, 1987 , p. 687 - 692 |
|
~94%
1-Methoxy-1-(Tr... CAS#:31469-15-5 |
| Literature: Schulz, William J.; Speier, John L. Synthesis, 1989 , # 3 p. 163 - 166 |
|
~95%
1-Methoxy-1-(Tr... CAS#:31469-15-5 |
| Literature: Schulz, William J.; Speier, John L. Synthesis, 1989 , # 3 p. 163 - 166 |
|
~4%
1-Methoxy-1-(Tr... CAS#:31469-15-5
Detail
|
| Literature: Tetrahedron Letters, , vol. 28, # 41 p. 4809 - 4812 |
|
~%
1-Methoxy-1-(Tr... CAS#:31469-15-5 |
| Literature: Journal of the Chemical Society [Section] D: Chemical Communications, , p. 136 - 137 |
| Precursor 9 | |
|---|---|
| DownStream 8 | |
CAS#:38923-57-8
CAS#:140901-63-9
CAS#:140901-57-1
CAS#:19980-35-9
CAS#:225918-07-0
CAS#:122-97-4| HS Code | 2931900090 |
|---|---|
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
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Chiral Brønsted acid catalyzed enantioselective Mannich-type reaction.
J. Am. Chem. Soc. 129 , 6756, (2007) Mannich-type reaction of ketene silyl acetals with aldimines proceeded catalytically by means of a phosphoric acid diester, derived from (R)-BINOL, as a chiral Brønsted acid to afford beta-amino ester... |
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Aldrichimica Acta 17 , 41, (1984)
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Polymer J. Tokyo 26 , 169, (1994)
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| MTDA |
| [(1-Methoxy-2-methylprop-1-en-1-yl)oxy](trimethyl)silane |
| 2-methyl-1-methoxy-1-trimethylsilyloxypropene |
| 1-Propene, 1-methoxy-2-methyl-1-(trimethylsilyloxy)- |
| methoxy-1-trimethylsilyloxy-2,2-dimethylethylene |
| 1-Methoxy-1-trimethylsilyloxy-2-methyl-1-propene |
| 1-Methoxy-2-methyl-1-(trimethylsiloxy)propene |
| 1-methoxy-2-methyl-1-trimethylsiloxy-1-propene |
| MFCD00010232 |
| 1-methoxy-1-trimethylsilyloxy-2-methylpropene |
| methyl trimethylsilyl dimethylketene acetal |
| DiMethylketene Methyl TriMethylsilyl Acetal |
| X1-2231 Fluid |
| Silane, ((1-methoxy-2-methyl-1-propenyl)oxy)trimethyl- |
| Silane, [(1-methoxy-2-methyl-1-propen-1-yl)oxy]trimethyl- |
| [(1-Methoxy-2-methyl-1-propen-1-yl)oxy](trimethyl)silane |
| 1-Methoxy-2-methyl-1-(trimethylsilyloxy)-1-propene |
| 1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene |
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- Shanghai Nianxing Industrial Co., Ltd
- China
- Product Name: DIMETHYLKETENEMETHYLTRIMETHYLSILYLACETAL
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- Hubei Changfu Chemical Co., Ltd.
- China
- Product Name: 1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene
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- Shanghai Jizhi Biochemical Technology Co., Ltd
- China
- Product Name: 1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene
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- Purity: 95.0%
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- Dayang Chem (Hangzhou) Co., Ltd.
- China
- Product Name: 1-Methoxy-2-methyl-1-(trimethylsiloxy)propene
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- Purity: 98.0%
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- Zhongshan Xingrui Chemical Co. , Ltd.
- China
- Product Name: 1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene
- Price: ￥Inquiry/25kg
- Purity: 99.0%
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