Methyl 2-bromo-2-methylpropionate

Modify Date: 2024-01-02 11:31:17

Methyl 2-bromo-2-methylpropionate Structure
Methyl 2-bromo-2-methylpropionate structure
Common Name Methyl 2-bromo-2-methylpropionate
CAS Number 23426-63-3 Molecular Weight 181.028
Density 1.4±0.1 g/cm3 Boiling Point 145.8±8.0 °C at 760 mmHg
Molecular Formula C5H9BrO2 Melting Point N/A
MSDS Chinese USA Flash Point 46.9±11.9 °C
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

 Names

Name methyl 2-bromo-2-methylpropanoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 145.8±8.0 °C at 760 mmHg
Molecular Formula C5H9BrO2
Molecular Weight 181.028
Flash Point 46.9±11.9 °C
Exact Mass 179.978592
PSA 26.30000
LogP 1.53
Vapour Pressure 4.8±0.3 mmHg at 25°C
Index of Refraction 1.455

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H226-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi
Risk Phrases R10;R36/37
Safety Phrases S26-S36
RIDADR UN 2929 6.1/PG 2
WGK Germany 3
Hazard Class 6.1, 3.0
HS Code 2915900090

 Synthetic Route

~%

Methyl 2-bromo-2-methylpropionate Structure

Methyl 2-bromo-...

CAS#:23426-63-3

Literature: Journal of the Chemical Society, , p. 1777 Journal of the American Chemical Society, , vol. 62, p. 1306

~%

Methyl 2-bromo-2-methylpropionate Structure

Methyl 2-bromo-...

CAS#:23426-63-3

Literature: Tetrahedron, , vol. 50, # 32 p. 9825 - 9830

~%

Methyl 2-bromo-2-methylpropionate Structure

Methyl 2-bromo-...

CAS#:23426-63-3

Literature: Journal of the American Chemical Society, , vol. 74, p. 1816,1818

~%

Methyl 2-bromo-2-methylpropionate Structure

Methyl 2-bromo-...

CAS#:23426-63-3

Literature: Tetrahedron, , vol. 50, # 32 p. 9825 - 9830

~%

Methyl 2-bromo-2-methylpropionate Structure

Methyl 2-bromo-...

CAS#:23426-63-3

Literature: Journal of Organic Chemistry, , vol. 43, p. 3687 - 3689

~%

Methyl 2-bromo-2-methylpropionate Structure

Methyl 2-bromo-...

CAS#:23426-63-3

Literature: Journal of the Chemical Society, , p. 1851,1853

~%

Methyl 2-bromo-2-methylpropionate Structure

Methyl 2-bromo-...

CAS#:23426-63-3

Literature: Journal of Organic Chemistry, , vol. 33, p. 4279 - 4281

~%

Methyl 2-bromo-2-methylpropionate Structure

Methyl 2-bromo-...

CAS#:23426-63-3

Literature: Bulletin de la Societe Chimique de France, , p. 678,683

~%

Methyl 2-bromo-2-methylpropionate Structure

Methyl 2-bromo-...

CAS#:23426-63-3

Literature: Journal of the American Chemical Society, , vol. 74, p. 1816,1818

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Articles1

More Articles
Reformatsky reaction of methyl ?-bromoisobutyrate with Schiff bases derived from salicylaldehyde and 2-hydroxynaphthalene-1-carbaldehyde.

Russ. J. Org. Chem. 40(6) , 834-836, (2004)

 Synonyms

Methyl 2-bromo-isobutyrate
Methyl |A-bromoisobutyrate
Methyl-2-bromo-isobutyric acid
EINECS 245-657-6
methyl 2-bromo-2,2-dimethylacetate
Methyl 2-bromo-2-methylpropionate
MFCD00017854
alpha-Bromoisobutyricacidmethylester
Methyl 2-Bromoisobutyrate
Methyl α-bromoisobutyrate
methyl 2-bromo-2-methyl-propionate
Propanoic acid,2-bromo-2-methyl-,methyl ester
Propanoic acid, 2-bromo-2-methyl-, methyl ester
methyl2-bromoisobutyrate
2-bromo-2-methylpropionic acid methyl ester
Methyl 2-bromo-2-methylpropanoate