Methyl 2-fluoro-2-methylpropionate

Modify Date: 2024-01-05 18:29:24

Methyl 2-fluoro-2-methylpropionate Structure
Methyl 2-fluoro-2-methylpropionate structure
Common Name Methyl 2-fluoro-2-methylpropionate
CAS Number 338-76-1 Molecular Weight 120.12200
Density 1.356g/cm3 Boiling Point N/A
Molecular Formula C5H9FO2 Melting Point N/A
MSDS N/A Flash Point N/A

 Names

Name methyl 2-fluoro-2-methylpropanoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.356g/cm3
Molecular Formula C5H9FO2
Molecular Weight 120.12200
Exact Mass 120.05900
PSA 26.30000
LogP 0.90750
Index of Refraction 1.369

 MSDS

Material Safety Data Sheet

Section1. Identification of the substance
Product Name: Methyl 2-fluoro-2-methylpropionate
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.

Section3. Composition/information on ingredients.
Ingredient name:Methyl 2-fluoro-2-methylpropionate
CAS number:338-76-1

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Store in closed vessels, refrigerated.
Storage:

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Appearance:Not specified
Boiling point:No data
No data
Melting point:
Flash point:No data
Density:No data
Molecular formula:C5H9FO2
Molecular weight:120.1

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, hydrogen fluoride.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
Non-harzardous for air and ground transportation.

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes F: Flammable;
Risk Phrases R10
Safety Phrases 16
RIDADR UN 3272
HS Code 2915900090

 Synthetic Route

~75%

Methyl 2-fluoro-2-methylpropionate Structure

Methyl 2-fluoro...

CAS#:338-76-1

Literature: Purrington, Suzanne T.; Woodard, Daniel L. Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3423 - 3424

~2%

Methyl 2-fluoro-2-methylpropionate Structure

Methyl 2-fluoro...

CAS#:338-76-1

Literature: Idemitsu Kosan Co., Ltd. Patent: US5527954 A1, 1996 ;

~59%

Methyl 2-fluoro-2-methylpropionate Structure

Methyl 2-fluoro...

CAS#:338-76-1

Literature: Amanetoullah, A. Ould; Chaabouni; Baklouti Synthetic Communications, 1996 , vol. 26, # 6 p. 1155 - 1161

~%

Methyl 2-fluoro-2-methylpropionate Structure

Methyl 2-fluoro...

CAS#:338-76-1

Literature: Israel Journal of Chemistry, , vol. 8, p. 925 - 933

~%

Methyl 2-fluoro-2-methylpropionate Structure

Methyl 2-fluoro...

CAS#:338-76-1

Literature: Journal of Organic Chemistry, , vol. 33, p. 4279 - 4281

~%

Methyl 2-fluoro-2-methylpropionate Structure

Methyl 2-fluoro...

CAS#:338-76-1

Literature: Russian Journal of Organic Chemistry, , vol. 29, # 9.1 p. 1450 - 1456 Zhurnal Organicheskoi Khimii, , vol. 29, # 9 p. 1746 - 1753

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Synonyms

ethyl 2-fluoroisobutyrate
Methyl 2-fluoro-2-methylpropanoate
methyl 2-fluoro-isobutyrate
METHYL 2-FLUORO-2-METHYLPROPIONATE
Propanoic acid,2-fluoro-2-methyl-,methyl ester
2-FLUORO-2-METHYL-PROPANOIC ACID,METHYL ESTER
methyl 2-fluoroisobutanoate
Methyl 2-Fluoro-2-methylpropionate