allyl-chloro-palladium
allyl-chloro-palladium structure
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Common Name | allyl-chloro-palladium | ||
|---|---|---|---|---|
| CAS Number | 12012-95-2 | Molecular Weight | 365.890 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C6H10Cl2Pd2 | Melting Point | 120°C (dec.) | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Room-temperature Stille cross-couplings of alkenyltin reagents and functionalized alkyl bromides that possess beta hydrogens.
J. Am. Chem. Soc. 125 , 3718, (2003) This communication describes a significant expansion in the scope of Stille reactions of Csp3-X electrophiles, specifically, that Pd/P(t-Bu)2Me catalyzes the room-temperature cross-coupling of a variety of functionalized, beta-hydrogen-containing alkyl bromid... |
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The first applications of carbene ligands in cross-couplings of alkyl electrophiles: sonogashira reactions of unactivated alkyl bromides and iodides.
J. Am. Chem. Soc. 125 , 13642, (2003) A Pd/N-heterocyclic carbene-based catalyst achieves the Sonogashira coupling of an array of functionalized, beta-hydrogen-containing alkyl bromides and iodides under mild conditions. By furnishing the first example of a nonphosphine-based palladium catalyst f... |
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Palladium-catalyzed hydroamination of 1,3-dienes: a colorimetric assay and enantioselective additions.
J. Am. Chem. Soc. 123 , 4366, (2001)
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Efficient Heck vinylation of aryl halides catalyzed by a new air-stable palladium-tetraphosphine complex.
J. Org. Chem. 66 , 5923, (2001)
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Palladium-catalyzed carbonylation of yne esters leading to gamma-alkylidene alpha,beta-unsaturated gamma-lactones.
Org. Lett. 7 , 4385, (2005) [reaction: see text] The reaction of yne esters with carbon monoxide (1 atm) in the presence of palladium complexes gives bicyclic unsaturated lactone derivatives in good to high yields. The 2-pyridinyloxy group is a good leaving group among leaving groups ex... |
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Suzuki cross-couplings of alkyl tosylates that possess beta hydrogen atoms: synthetic and mechanistic studies.
Angew. Chem. Int. Ed. Engl. 41 , 3910, (2002)
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Superhydrophobicity of nanostructured carbon films in a wide range of pH values.
Angew. Chem. Int. Ed. Engl. 42 , 4217, (2003)
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J. Org. Chem. 59 , 5034, (1994)
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Synthesis , 1683, (2007)
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European J. Org. Chem. , 3122, (2007)
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