3,5-Bis-tert-butylsalicylic acid
3,5-Bis-tert-butylsalicylic acid structure
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Common Name | 3,5-Bis-tert-butylsalicylic acid | ||
|---|---|---|---|---|
| CAS Number | 19715-19-6 | Molecular Weight | 250.33300 | |
| Density | 1.07g/cm3 | Boiling Point | 335.6ºC at 760mmHg | |
| Molecular Formula | C15H22O3 | Melting Point | 157-162 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 179 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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On the Kolbe-Schmitt synthesis of pharmacologically useful salicylates: carboxylation of 2,4-di-t-butylphenol and identification and reduction of the formation of 2,2'-dihydroxy-3,3',5,5'-tetra-t-butylbiphenyl in the synthesis of 3,5-di-t-butylsalicylic acid.
J. Pharm. Sci. 80(8) , 810-1, (1991) The initial yield of 3,5-di-t-butylsalicylic acid obtained via Kolbe-Schmitt carboxylation of the potassium salt of 2,4-di-t-butylphenol was less than 1% and was accompanied by a 65% yield of 2,2'-dihydroxy-3,3',5,5'- tetra-t-butylbiphenyl, a dimer of the 2,4... |
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Polyfluorinated Pd(II)-3,5-di-tert-butylsalicylaldimenes complexes: synthesis, structure, spectroscopy, redox behaviors and catalytic activity.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 107 , 31-8, (2013) A series of new polyfluorinated palladium(II) complexes (7-12) of N-polyfluorophenyl-3,5-di-tert-butylsalicylaldimines (1-6) have been synthesized. They were characterized by analytical, spectroscopic (UV/Vis, IR, (1)H NMR, and ESR), electrochemical methods a... |
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Photoinduced proton transfers in 3, 5-di-tert-butylsalicylic acid.
J. Phys. Chem. 99(32) , 12103-12108, (1995)
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A first example of macromolecular Ti (IV) Lewis acid in the catalytic enantioselective Mukaiyama reaction.
Tetrahedron Asymmetry 9(9) , 1479-1482, (1998)
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