Isopentenyl pyrophosphate trilithium salt

Isopentenyl pyrophosphate trilithium salt Structure
Isopentenyl pyrophosphate trilithium salt structure
Common Name Isopentenyl pyrophosphate trilithium salt
CAS Number 18687-43-9 Molecular Weight 263.89100
Density N/A Boiling Point N/A
Molecular Formula C5H9Li3O7P2 Melting Point N/A
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

An improved synthesis of isopentenyl pyrophosphate.

Biochem. J. 105 , 545-547, (1967)

1. Isopentenol was converted into isopentenyl phosphate with phosphoryl chloride in ether containing pyridine. 2. The isopentenyl phosphate reacted in 2-methylpropan-2-ol-water with morpholine and dicyclohexylcarbodi-imide to give isopentenyl phosphoromorphol...

The biosynthesis of rubber. Incorporation of mevalonate and isopentenyl pyrophosphate into rubber by Hevea brasiliensis-latex fractions.

Biochem. J. 89(3) , 565-74, (1963)

The biosynthesis of isoprenoids and the mechanisms regulating it in plants.

Biosci. Biotechnol. Biochem. 75 , 1219-1225, (2011)

Plants synthesize isopentenyl diphosphate (IPP) via the mevalonate pathway and the methylerythritol phosphate (MEP) pathway. IPP is condensed to its allylic isomer, dimethylallyl diphosphate, to yield geranylgeranyl diphosphate, a common precursor for the pro...

Type-2 isopentenyl diphosphate isomerase: evidence for a stepwise mechanism.

J. Am. Chem. Soc. 133 , 19017-19019, (2011)

Isopentenyl diphosphate isomerase (IDI) catalyzes the interconversion of isopentenyl diphosphate (IPP) and dimethylallyl diphosphate (DMAPP). These two molecules are the building blocks for construction of isoprenoid carbon skeletons in nature. Two structural...

Type II isopentenyl diphosphate isomerase: probing the mechanism with alkyne/allene diphosphate substrate analogues.

Biochemistry 49 , 6228-6233, (2010)

Isopentenyl diphosphate isomerase (IDI) catalyzes the interconversion of isopentenyl diphosphate (IPP) and dimethylallyl diphosphate (DMAPP), the basic five-carbon building blocks of isoprenoid molecules. Two structurally unrelated classes of IDIs are known. ...

Isopentenyl diphosphate isomerase catalyzed reactions in D2O: product release limits the rate of this sluggish enzyme-catalyzed reaction.

J. Am. Chem. Soc. 134 , 6568-6570, (2012)

The E. coli isopentenyl diphosphate isomerase (IDI) catalyzed reaction of isopentenyl diphosphate (IPP) in D(2)O gives a 66% yield of dimethylallyl diphosphate labeled with deuterium at the (E)-methyl group (d-DMAPP) and a 34% yield of IPP labeled with 1 mol ...

New aspects of rubber biosynthesis. Archer B L and Audrey B G

Bot. J. Linn. Soc. 94 , 181-196, (1987)