Potassium monoethyl malonate
Potassium monoethyl malonate structure
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Common Name | Potassium monoethyl malonate | ||
|---|---|---|---|---|
| CAS Number | 6148-64-7 | Molecular Weight | 170.205 | |
| Density | N/A | Boiling Point | 237.2ºC at 760 mmHg | |
| Molecular Formula | C5H7KO4 | Melting Point | 194 °C (dec.)(lit.) | |
| MSDS | Chinese USA | Flash Point | 100.8ºC | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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The decarboxylative Blaise reaction.
J. Org. Chem. 72(26) , 10261-3, (2007) Reaction of aryl nitriles with potassium ethyl malonate in the presence of zinc chloride and a catalytic amount of Hünig's base provided beta-amino acrylates in moderate to good yield. Compared to the classical Blaise reaction, this reaction is safer (endothe... |
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Ethyl tert-Butyl Malonate. Strube RE.
Organometallic Syntheses , 34-34, (1963)
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A process for the synthesis of ß-ketoesters using in-situ generated (trimethylsilyl) malonates Wang X, et al.
Tetrahedron Lett. 35(50) , 9323-26, (1994)
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