Dibutyltin oxide

Dibutyltin oxide Structure
Dibutyltin oxide structure
Common Name Dibutyltin oxide
CAS Number 818-08-6 Molecular Weight 248.938
Density 1,5 g/cm3 Boiling Point >300°C
Molecular Formula C8H18OSn Melting Point ≥300 °C(lit.)
MSDS Chinese USA Flash Point 81-83°C
Symbol GHS05 GHS06 GHS08 GHS09
GHS05, GHS06, GHS08, GHS09
Signal Word Danger

Copolyesters made from 1,4-butanediol, sebacic acid, and D-glucose by melt and enzymatic polycondensation.

Biomacromolecules 16(3) , 868-79, (2015)

Biotechnologically accessible 1,4-butanediol and vegetal oil-based diethyl sebacate were copolymerized with bicyclic acetalized D-glucose derivatives (Glux) by polycondensation both in the melt at high temperature and in solution at mild temperature mediated ...

Hydrogen-bond-mediated self-assembly of 26-membered diaza tetraester crowns of 3,5-disubstituted 1H-pyrazole. Dimerization study in the solid state and in CDCl3 solution.

J. Org. Chem. 76(20) , 8223-31, (2011)

By using an improved synthetic method reported earlier, the cyclic stannoxanes obtained from RN-diethanolamine (R = Me, Bu) and dibutyltin oxide have been reacted with 1H-pyrazole-3,5-dicarbonyl dichloride to afford 26-membered diaza tetraester crowns (1, R =...

Dibutyltin oxide--phenyl isocyanate system for regioselective phenylcarbamoylation of the hydroxy-groups of ribonucleosides.

Nucleic Acids Symp. Ser. (8) , s7-8, (1980)

For partial phenylcarbamoylation of the hydroxy-groups of ribonucleosides, dibutyltin oxide--phenyl isocyanate system was found to be surperior to the bis(tributyltin) oxide--phenyl isocyanate system from the standpoint of reaction procedures including isolat...

[Preparation and spectroscopic studies of diorganotin(IV) complexes with adenosine and related compounds].

Acta Pharm. Hung. 70(3-6) , 119-30, (2000)

Nine complexes of adenosine and related compounds (adenosine-5'-monophosphate, adenosine-5'-triphosphate, 1-methyl-adenosine, pyridoxal-5-phosphate and beta-nicotinamide-adenine-dinucleotide-phosphoric acid) with di-n-butyltin(IV) oxide and/or di-n-butytin(IV...

Synthesis of 2- and 4-nitrophenyl beta-glycosides of beta-(1-->4)- D-xylo-oligosaccharides of dp 2-4.

Carbohydr. Res. 277(2) , 231-44, (1995)

2- and 4-Nitrophenyl beta-D-xylopyranosides (4 and 5) were transformed, via dibutyltin oxidemediated acylation, into the corresponding 2,3-di-O-benzoyl derivatives 11 and 15. Xylobiose and xylotriose were easily isolated by charcoal column chromatography from...

A mild and selective method for cleavage of O-acetyl groups with dibutyltin oxide.

Carbohydr. Res. 337(19) , 1763-7, (2002)

A mild and efficient neutral method for the cleavage of O-acetyl groups with dibutyltin oxide has been developed. This method is especially useful in the synthesis of glycosides containing base- or acid-sensitive multifunctional groups.

Application of dibutyltin oxide method to regioselective acylation and alkylation of tylosin at C-4''.

Chem. Pharm. Bull. 37(4) , 861-5, (1989)

4''-O-Acyl-, 4''-O-alkyl- and 4''-deoxy-tylosin derivatives were synthesized using 2'-O-acetyl-3'',4''-O-(dibutyl-stannio)tylosin as a synthetic intermediate. The in vitro biological evaluation showed that the new derivatives were active against macrolide-res...

Synthesis of (1-->4)-beta-D-xylo-oligosaccharides of dp 4-10 by a blockwise approach.

Carbohydr. Res. 278(2) , 301-13, (1995)

Dibutyltin oxide-mediated regioselective chloroacetylation of methyl 1-thio-beta-xylobioside, followed by treatment of the product with 4-methylbenzoyl chloride-pyridine, gave methyl 4-O-chloroacetyl-2,3-di-O-(4-methylbenzoyl)-beta-D-xylopyranosyl-(1-->4) -2....

[Experimental toxicity of indium formate and indium formate- dibutyltin oxide mixture (90-10) in the rat].

J. Toxicol. Clin. Exp. 8(4) , 273-88, (1988)

[Experimental toxicity of indium formate and a mixture of indium formate-dibutyltin oxide (90-10) in the rat].

J. Toxicol. Clin. Exp. 8(6) , 401-18, (1988)