(+)-Pirkle's Alcohol
(+)-Pirkle's Alcohol structure
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Common Name | (+)-Pirkle's Alcohol | ||
|---|---|---|---|---|
| CAS Number | 60646-30-2 | Molecular Weight | 276.253 | |
| Density | 1.3±0.1 g/cm3 | Boiling Point | 423.1±45.0 °C at 760 mmHg | |
| Molecular Formula | C16H11F3O | Melting Point | 132-135ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 165.2±19.8 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Separation of racemic 1-(9-Anthryl)-2,2,2-trifluoroethanol by sub-/supercritical fluid chromatography.
Methods Mol. Biol. 970 , 249-55, (2013) Supercritical fluid chromatography is an environmentally benign separation technology due to the use of carbon dioxide modified with organic solvents as the mobile phase. It has found widespread use in the separation of chiral compounds based on the relative ... |
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Adsorption of the enantiomers of 2,2,2-trifluoro-1-(9-anthryl)-ethanol on silica-bonded chiral quinidine-carbamate.
J. Chromatogr. A. 1059(1-2) , 43-52, (2004) The adsorption isotherms of the enantiomers of 2,2,2-trifluoro-1-(9-anthryl)-ethanol from a toluene-acetonitrile solution onto a Chiris Chiral AX:QD1 column were measured using the pulse method. The isotherm data were modeled with a bi-Langmuir isotherm model... |
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Gas chromatographic-mass spectrometric determination of ibuprofen enantiomers in human plasma using R(-)-2,2,2-trifluoro-1-(9-anthryl)ethanol as derivatizing reagent.
J. Chromatogr. B, Biomed. Appl. 656(2) , 441-6, (1994) A relatively rapid, inexpensive, sensitive and stereospecific gas chromatographic-mass spectrometric method was developed for the quantification of S(+) and R(-)-ibuprofen in human plasma. This method uses a commercially available internal standard and has no... |
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Chromatographic behavior of the enantiomers of 2,2,2-trifluoro-1-(9-anthryl)ethanol on a quinidine-carbamate chiral stationary phase.
J. Chromatogr. A. 1091(1-2) , 183-6, (2005) The enantioseparation of 2,2,2-trifluoro-1-(9-anthryl)ethanol on silica-bonded quinidine carbamate was examined under linear chromatographic conditions. The significant impact of nonselective adsorption on the retention was demonstrated. The influences of a p... |
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A screening method for chiral selectors that does not require covalent attachment.
J. Am. Chem. Soc. 128(7) , 2208-9, (2006) A high-throughput screening protocol is proposed for chiral selector discovery. It is modeled after the protocol for biological screening of candidate drugs from chemical libraries. The procedure works based on target distribution between an aqueous phase and... |
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The use of poly(sodium N-undecanoyl-L-leucylvalinate), poly(sodium N-undecanoyl-L-leucinate) and poly(sodium N-undecanoyl-L-valinate) surfactants as chiral selectors for determination of enantiomeric composition of samples by multivariate regression modeling of fluorescence spectral data.
J. Fluoresc. 16(5) , 659-70, (2006) Steady-state fluorescence spectroscopy was employed to investigate the use of chiral polymeric surfactants as chiral selectors in chiral analysis by multivariate regression modeling of spectral data. Partial-least-squares regression modeling (PLS-1) was used ... |
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J. Chromatogr. A. 123 , 400, (1976)
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J. Org. Chem. 42 , 384, 1370, (1977)
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J. Org. Chem. 43 , 378, (1978)
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J. Org. Chem. 42 , 2436, (1977)
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