3-(2,6-Diisopropylphenyl)-5,6,7,8-tetrahydro-4H-cyclohepta[d]thiazol-3-ium perchlorate
![3-(2,6-Diisopropylphenyl)-5,6,7,8-tetrahydro-4H-cyclohepta[d]thiazol-3-ium perchlorate Structure](https://image.chemsrc.com/caspic/295/1062158-66-0.png)
3-(2,6-Diisopropylphenyl)-5,6,7,8-tetrahydro-4H-cyclohepta[d]thiazol-3-ium perchlorate structure
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Common Name | 3-(2,6-Diisopropylphenyl)-5,6,7,8-tetrahydro-4H-cyclohepta[d]thiazol-3-ium perchlorate | ||
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| CAS Number | 1062158-66-0 | Molecular Weight | 413.95900 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C20H28ClNO4S | Melting Point | 105-108 °C | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Palladium-catalyzed C-allylation of benzoins and an NHC-catalyzed three component coupling derived thereof: compatibility of NHC- and Pd-catalysts.
Org. Lett. 10 , 4243-4246, (2008) A large range of benzoins was successfully applied as C-nucleophiles in the palladium-catalyzed allylic alkylation with several allyl acetates, resulting in functionalized tertiary homoallylic alcohols. A number of unsymmetrical benzoins can be coupled with h... |
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N-heterocyclic carbene-catalyzed hydroacylation of unactivated double bonds.
J. Am. Chem. Soc. 131 , 14190-14190, (2009) An intramolecular N-heterocyclic carbene (NHC)-catalyzed hydroacylation of unactivated double bonds is reported. Systematic variation of the catalyst structure revealed an N-mesitylthiazolylidene annulated with a seven-membered ring to be especially reactive.... |
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N-heterocyclic carbene-catalyzed cascade reaction involving the hydroacylation of unactivated alkynes.
J. Am. Chem. Soc. 132 , 5970-5971, (2010) The N-heterocyclic carbene (NHC)-catalyzed hydroacylation of unactivated alkynes to provide alpha,beta-unsaturated ketones is reported. In addition, a rare case of an efficient and selective dually NHC-catalyzed cascade reaction involving the hydroacylation o... |
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Diastereoselective Synthesis of Trifluoromethylated γ-Butyrolactones via N-Heterocyclic Carbene-catalyzed Conjugated Umpolung of a,ß-unsaturated Aldehydes. Hirano, K., et al.
Adv. Synth. Catal. 350 , 984-988, (2008)
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