2,2,6,6-Tetramethylheptane-3,5-dione
2,2,6,6-Tetramethylheptane-3,5-dione structure
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Common Name | 2,2,6,6-Tetramethylheptane-3,5-dione | ||
|---|---|---|---|---|
| CAS Number | 1118-71-4 | Molecular Weight | 184.28 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 202.8±0.0 °C at 760 mmHg | |
| Molecular Formula | C11H20O2 | Melting Point | 19 °C | |
| MSDS | Chinese USA | Flash Point | 67.2±0.0 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Ullmann diaryl ether synthesis: rate acceleration by 2,2,6,6-tetramethylheptane-3,5-dione.
Org. Lett. 4(9) , 1623-6, (2002) [reaction: see text]. In the copper salt catalyzed ether formation from aryl bromides or iodides and phenols, 2,2,6,6-tetramethylheptane-3,5-dione (TMHD) was found to greatly accelerate the ordinarily difficult reaction, making it occur under more moderate te... |
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26Mg as a probe in research on the role of magnesium in nutrition and metabolism.
Fed. Proc. 41(10) , 2709-13, (1982) The potential of the stable isotope 26Mg (natural abundance 11.01 atom %) as a biological tracer has been explored using neutron activation (NA) and mass spectrometry (MS) for detection. The high natural abundance of this isotope restricts its utility to purp... |
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Ultrafine 239PuO2 aerosol generation, characterization and short-term inhalation study in the rat.
Health Phys. 39(3) , 505-19, (1980)
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Wavelength dependent photofragmentation patterns of tris(2,2,6,6-tetramethyl-3,5-heptanedionato)Ln (III) (Ln = Eu, Tb, Gd) in a molecular beam.
J. Phys. Chem. A 110(25) , 7751-4, (2006) Laser photoionization and ligand photodissociation in Ln(thd)(3) (Ln = Eu, Tb, Gd; thd = 2,2,6,6-tetramethyl-3,5-heptanedionato) are studied in a molecular beam via time-of-flight mass spectrometry. The fragmentation patterns are strongly wavelength dependent... |
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Tetrahedron 48 , 6909, (1992)
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On the role of the bridging dicyanamidobenzene ligand in a new binuclear ruthenium complex: [{Ru(tpy)(thd)}2(mu-dicyd)][PF6] with tpy = 2,2':6',2' '-terpyridine and thd = 2,2,6,6-tetramethyl-3,5-heptanedione.
Inorg. Chem. 45(23) , 9332-45, (2006) The dicyanamidobenzene-bridge diruthenium complex [{Ru(tpy)(thd)}(2)(mu-dicyd)][PF(6)] ([3][PF(6)]) (dicyd = 1,4-dicyanamidobenzene, tpy = 2,2':6',2' '-terpyridine, thd = 2,2,6,6-tetramethyl-3,5-heptanedione) and its mononuclear counterpart [Ru(tpy)(thd)(Ipcy... |