Methyl DAST
Methyl DAST structure
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Common Name | Methyl DAST | ||
|---|---|---|---|---|
| CAS Number | 3880-03-3 | Molecular Weight | 133.13600 | |
| Density | 1.23g/cm3 | Boiling Point | 117.5ºC(lit.) | |
| Molecular Formula | C2H6F3NS | Melting Point | -78.7ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 10ºC | |
| Symbol |
GHS02, GHS05, GHS07 |
Signal Word | Danger | |
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An improved method for the synthesis of protected glycosyl fluorides from thioglycosides using N,N-diethylaminosulfur trifluoride (DAST).
Carbohydr. Res. 359 , 81-91, (2012) The direct conversion of thioglycosides to glycosyl fluorides frequently used in oligosaccharide synthesis was examined using N,N-diethylaminosulfur trifluoride (DAST). Although the reaction proceeded without N-bromosuccinimide (NBS), in some cases it was fou... |
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Reaction of aminosulfur trifluorides with alcohols: inversion vs. retention Shellhamer, D. F.; et al.
J. Chem. Soc. 5 , 973-977, (1996)
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Synthesis of new fluorinated podophyllotoxin derivatives He, X. Y.; Yi, T.; Wang, Y. G.
Chin. Chem. Lett. 2nd ed., 15 , 131-134, (2004)
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