SnAP Pip Reagent
SnAP Pip Reagent structure
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Common Name | SnAP Pip Reagent | ||
|---|---|---|---|---|
| CAS Number | 1557287-99-6 | Molecular Weight | 463.29 | |
| Density | 1.108 g/mL | Boiling Point | N/A | |
| Molecular Formula | C20H44N2O2Sn | Melting Point | N/A | |
| MSDS | USA | Flash Point | N/A | |
| Symbol |
GHS06, GHS09 |
Signal Word | Danger | |
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SnAP reagents for the transformation of aldehydes into substituted thiomorpholines--an alternative to cross-coupling with saturated heterocycles.
Angew. Chem. Int. Ed. Engl. 52(6) , 1705-8, (2013)
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SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes.
Nature Chemistry 6(4) , 310-4, (2014) Interest in saturated N-heterocycles as scaffolds for the synthesis of bioactive molecules is increasing. Reliable and predictable synthetic methods for the preparation of these compounds, especially medium-sized rings, are limited. We describe the developmen... |
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One-step synthesis of saturated spirocyclic N-heterocycles with stannyl amine protocol (SnAP) reagents and ketones.
J. Am. Chem. Soc. 136(51) , 17726-9, (2014) The combination of cyclic ketones and stannyl amine protocol (SnAP) reagents affords saturated, spirocyclic N-heterocycles under operationally simple reaction conditions. The resulting, N-unprotected spirocyclic amines are in great demand as scaffolds for dru... |
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SnAP reagents for the synthesis of piperazines and morpholines.
Org. Lett. 16(4) , 1236-9, (2014) Substituted piperazines and morpholines are valuable structural motifs in biologically active compounds, but are not easily prepared by contemporary cross-coupling approaches. In this report, we introduce SnAP reagents for the transformation of aldehydes into... |