1-(Cyclopenta-2,4-dien-1-ylidene)-N,N-dimethylmethanamine
1-(Cyclopenta-2,4-dien-1-ylidene)-N,N-dimethylmethanamine structure
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Common Name | 1-(Cyclopenta-2,4-dien-1-ylidene)-N,N-dimethylmethanamine | ||
|---|---|---|---|---|
| CAS Number | 696-68-4 | Molecular Weight | 121.180 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 205.3±9.0 °C at 760 mmHg | |
| Molecular Formula | C8H11N | Melting Point | 64-66ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 70.3±15.6 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
|
Asymmetric synthesis of metallocenes through enantioselective addition of organolithium reagents to 6-(dimethylamino)fulvene.
J. Org. Chem. 67(10) , 3355-9, (2002) Enantioselective addition of aryllithiums 2a-d (Ar = Ph (a), 2-MeC(6)H(4) (b), 2-MeOC(6)H(4) (c), 1-naphthyl (d)) to 6-(dimethylamino)fulvene (1) in the presence of (-)-sparteine in toluene at -78 degrees C generated chiral cyclopentadienyllithiums (4) substi... |
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