1-(Cyclopenta-2,4-dien-1-ylidene)-N,N-dimethylmethanamine structure
|
Common Name | 1-(Cyclopenta-2,4-dien-1-ylidene)-N,N-dimethylmethanamine | ||
|---|---|---|---|---|
| CAS Number | 696-68-4 | Molecular Weight | 121.180 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 205.3±9.0 °C at 760 mmHg | |
| Molecular Formula | C8H11N | Melting Point | 64-66ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 70.3±15.6 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | 6-(Dimethylamino)fulvene |
|---|---|
| Synonym | More Synonyms |
| Density | 1.0±0.1 g/cm3 |
|---|---|
| Boiling Point | 205.3±9.0 °C at 760 mmHg |
| Melting Point | 64-66ºC(lit.) |
| Molecular Formula | C8H11N |
| Molecular Weight | 121.180 |
| Flash Point | 70.3±15.6 °C |
| Exact Mass | 121.089149 |
| PSA | 3.24000 |
| LogP | 1.61 |
| Vapour Pressure | 0.3±0.4 mmHg at 25°C |
| Index of Refraction | 1.633 |
| InChIKey | UJXXVGXQTXQALL-UHFFFAOYSA-N |
| SMILES | CN(C)C=C1C=CC=C1 |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xi: Irritant; |
| Risk Phrases | R36/37/38 |
| Safety Phrases | 26-37/39 |
| RIDADR | NONH for all modes of transport |
| HS Code | 2921300090 |
|
~64%
1-(Cyclopenta-2... CAS#:696-68-4 |
| Literature: Sanz, Dionisia; Perez-Torralba, Marta; Alarcon, Sergio Hugo; Claramunt, Rosa Maria; Foces-Foces, Concepcion; Elguero, Jose Journal of Organic Chemistry, 2002 , vol. 67, # 5 p. 1462 - 1471 |
|
~78%
1-(Cyclopenta-2... CAS#:696-68-4 |
| Literature: Lou, Yan; Chang, Joanne; Jorgensen, Jeffrey; Lemal, David M. Journal of the American Chemical Society, 2002 , vol. 124, # 51 p. 15302 - 15307 |
|
~%
1-(Cyclopenta-2... CAS#:696-68-4 |
| Literature: Tetrahedron Letters, , vol. 31, # 4 p. 545 - 548 |
|
~%
1-(Cyclopenta-2... CAS#:696-68-4 |
| Literature: Tetrahedron Letters, , vol. 31, # 4 p. 545 - 548 |
|
~%
1-(Cyclopenta-2... CAS#:696-68-4 |
| Literature: Tetrahedron Letters, , vol. 31, # 4 p. 545 - 548 |
|
~%
1-(Cyclopenta-2... CAS#:696-68-4 |
| Literature: Justus Liebigs Annalen der Chemie, , vol. 641, p. 1 - 39 |
|
~%
1-(Cyclopenta-2... CAS#:696-68-4 |
| Literature: Angewandte Chemie, , vol. 75, p. 35 - 46 |
| Precursor 9 | |
|---|---|
| DownStream 5 | |
| HS Code | 2921300090 |
|---|---|
| Summary | 2921300090 other cyclanic, cyclenic or cyclotherpenic mono- or polyamines, and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0% |
|
Asymmetric synthesis of metallocenes through enantioselective addition of organolithium reagents to 6-(dimethylamino)fulvene.
J. Org. Chem. 67(10) , 3355-9, (2002) Enantioselective addition of aryllithiums 2a-d (Ar = Ph (a), 2-MeC(6)H(4) (b), 2-MeOC(6)H(4) (c), 1-naphthyl (d)) to 6-(dimethylamino)fulvene (1) in the presence of (-)-sparteine in toluene at -78 deg... |
| 1-(Cyclopenta-2,4-dien-1-yliden)-N,N-dimethylmethanamin |
| 1-cyclopenta-2,4-dien-1-ylidene-N,N-dimethylmethanamine |
| Methanamine, 1-(2,4-cyclopentadien-1-ylidene)-N,N-dimethyl- |
| 1-(Cyclopenta-2,4-dien-1-ylidene)-N,N-dimethylmethanamine |
| MFCD00013275 |
| 1-(2,4-Cyclopentadien-1-ylidene)-N,N-dimethylmethanamine |
| Methanamine, 1- (2,4-cyclopentadien-1-ylidene)-N,N-dimethyl- |