Bis(triphenylphosphine)iminium chloride

Bis(triphenylphosphine)iminium chloride Structure
Bis(triphenylphosphine)iminium chloride structure
Common Name Bis(triphenylphosphine)iminium chloride
CAS Number 21050-13-5 Molecular Weight 574.031
Density N/A Boiling Point N/A
Molecular Formula C36H30ClNP2 Melting Point 270-272 °C(lit.)
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

Novel organic solvents for electrochemistry at the liquid/liquid interface.

Analyst 140(6) , 1947-54, (2015)

Two-phase voltammetry has been carried out using a reverse cell configuration, i.e. with the lower density organic solvent on the top of the aqueous solution in the cell, where the organic solvents contain either nitrile or ketone functional groups. The trans...

Cu nanoparticles electrodeposited at liquid-liquid interfaces: a highly efficient catalyst for the hydrogen evolution reaction.

Chemistry 21(12) , 4585-9, (2015)

The electrochemical deposition of Cu nanoparticles with an average diameter of approximately 25-35 nm has been reported at liquid-liquid interfaces by using the organic-phase electron-donor decamethylferrocene (DMFc). The electrodeposited Cu nanoparticles dis...

A nitrate-selective electrode based on bis(triphenylphosphine)iminium salts.

Talanta 36 , 966-968, (1989)

A nitrate-sensitive electrode based on the ionic associates between bis(triphenylphosphine)iminium and nitrate ions in nitrobenzene solution is proposed. The electrode can be used for determinations of 10(-5) 0.1M nitrate in aqueous solutions.

Tandem synthesis of alternating polyesters from renewable resources.

Nat. Commun. 2 , 586, (2011)

The vast majority of commodity materials are obtained from petrochemical feedstocks. These resources will plausibly be depleted within the next 100 years, and the peak in global oil production is estimated to occur within the next few decades. In this regard,...

Indomethacin ion-selective electrode based on a bis(triphenylphosphoranylidene)ammonium-indomethacin complex.

Analyst 116(8) , 811-4, (1991)

The properties of an ion-selective electrode for indomethacin based on the bis(triphenylphosphoranylidene)ammonium-indomethacin ion-pair complex in a poly(vinyl chloride) membrane are described. The detection limit found for indomethacin at pH 7.0 was 2 x 10(...

Physicochemical characterization of sildenafil: ionization, lipophilicity behavior, and ionic-partition diagram studied by two-phase titration and electrochemistry. Giraulta HH, et.al.

Helv. Chim. Acta 83 , 1465, (2000)

Voltammetric determination of extreme standard Gibbs ion transfer energy. Olaya AJ, et.al.

J. Electroanal. Chem. 644 (1) , 60-66, (2010)