2-Methylimidazole

2-Methylimidazole Structure
2-Methylimidazole structure
Common Name 2-Methylimidazole
CAS Number 693-98-1 Molecular Weight 82.104
Density 1.1±0.1 g/cm3 Boiling Point 267-268 ºC
Molecular Formula C4H6N2 Melting Point 142-145 ºC
MSDS Chinese USA Flash Point 155 ºC
Symbol GHS05 GHS07 GHS08
GHS05, GHS07, GHS08
Signal Word Danger

Development of a novel magnetic molecularly imprinted polymer coating using porous zeolite imidazolate framework-8 coated magnetic iron oxide as carrier for automated solid phase microextraction of estrogens in fish and pork samples.

J. Chromatogr. A. 1365 , 35-44, (2014)

A high-performance magnetic molecularly imprinted polymer (MIP) coating using zeolite imidazolate framework-8 coated magnetic iron oxide (Fe3O4@ZIF-8) as a carrier was developed for simultaneous automated solid phase microextraction of four estrogens in 24 fo...

A new strategy to determine the protein mutation site using matrix-assisted laser desorption ionization in-source decay: derivatization by ionic liquid.

Anal. Chim. Acta 865 , 31-8, (2015)

Matrix-assisted laser desorption ionization (MALDI) time-of-flight mass spectrometry (TOF-MS) can be considered as state of the art in the field of proteins and peptides analysis. In this work, we have designed an ionic liquid derivative strategy to obtain ab...

Design of Zeolitic Imidazolate Framework Derived Nitrogen-Doped Nanoporous Carbons Containing Metal Species for Carbon Dioxide Fixation Reactions.

ChemSusChem 8 , 3905-12, (2015)

Various N-doped nanoporous carbons containing metal species were prepared by direct thermal conversion of zeolitic imidazolate frameworks (ZIFs; ZIF-7, -8, -9, and -67) at different temperatures (600, 800, and 1000 °C). These materials were utilized as bifunc...

Comparative chemometric modeling of cytochrome 3A4 inhibitory activity of structurally diverse compounds using stepwise MLR, FA-MLR, PLS, GFA, G/PLS and ANN techniques.

Eur. J. Med. Chem. 44 , 2913-22, (2009)

Twenty-eight structurally diverse cytochrome 3A4 (CYP3A4) inhibitors have been subjected to quantitative structure-activity relationship (QSAR) studies. The analyses were performed with electronic, spatial, topological, and thermodynamic descriptors calculate...

High-performance Polymer Membranes with Multi-functional Amphiphilic Micelles for CO2 Capture.

ChemSusChem 8 , 3783-92, (2015)

Herein, we report a high performance polymer membrane with simultaneously large improvements in the CO2 permeability and CO2/N2 selectivity. These improvements are obtained by incorporation of a multi-functional amphiphilic comb copolymer micelle, that is, po...

Asymmetric Supercapacitors Using 3D Nanoporous Carbon and Cobalt Oxide Electrodes Synthesized from a Single Metal-Organic Framework.

ACS Nano 9 , 6288-96, (2015)

Nanoporous carbon and nanoporous cobalt oxide (Co3O4) materials have been selectively prepared from a single metal-organic framework (MOF) (zeolitic imidazolate framework, ZIF-67) by optimizing the annealing conditions. The resulting ZIF-derived carbon posses...

Metal oxide-coated three-dimensional graphene prepared by the use of metal-organic frameworks as precursors.

Angew. Chem. Int. Ed. Engl. 53(5) , 1404-9, (2014)

A simple method for the preparation of metal-oxide-coated three-dimensional (3D) graphene composites was developed. The metal-organic frameworks (MOFs) that served as the precursors of the metal oxides were first synthesized on the 3D graphene networks (3DGNs...

Significantly Enhanced Separation using ZIF-8 Membranes by Partial Conversion of Calcined Layered Double Hydroxide Precursors.

ChemSusChem 8 , 3582-6, (2015)

Significantly enhanced H2 /CH4 (ca. 80) selectivity was realized by effective suppression of the framework flexibility of a prepared ZIF-8 membrane. Initially a ZnO buffer layer consisting of 20 nm-sized ZnO-nanoparticle aggregates was fabricated by controlle...

Fabrication of fluorescent SiO2@zeolitic imidazolate framework-8 nanosensor for Cu(2+) detection.

Analyst 140(2) , 623-9, (2014)

A simple strategy to fabricate a fluorescent SiO2@zeolitic imidazolate framework-8 (ZIF-8) core-shell nanosensor for Cu(2+) detection was demonstrated in this work. The nanosensor was synthesized using carboxyl-functionalized SiO2 nanoparticles (SiO2 NPs) as ...

Copper-catalyzed N-arylation of imidazoles and benzimidazoles.

J. Org. Chem. 72 , 6190, (2007)

4,7-Dimethoxy-1,10-phenanthroline (L1c) was found to be an efficient ligand for the copper-catalyzed N-arylation of imidazoles and benzimidazoles with both aryl iodides and bromides under mild conditions. Further optimization of the system has revealed that t...