Chemsuschem Chemistry And Sustainability, Energy & Materials 2015-11-01

High-performance Polymer Membranes with Multi-functional Amphiphilic Micelles for CO2 Capture.

Sang Jin Kim, Harim Jeon, Dong Jun Kim, Jong Hak Kim

Index: ChemSusChem 8 , 3783-92, (2015)

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Abstract

Herein, we report a high performance polymer membrane with simultaneously large improvements in the CO2 permeability and CO2/N2 selectivity. These improvements are obtained by incorporation of a multi-functional amphiphilic comb copolymer micelle, that is, poly(dimethylsiloxane)-g-poly(oxyethylene methacrylate) (PDMS-g-POEM), into a poly(amide-b-ethylene oxide) (Pebax) matrix. Both CO2 and N2 permeabilities continuously increased with PDMS-g-POEM content, whereas the CO2/N2 selectivity increased up to 40 wt % of PDMS-g-POEM, which enabled the maximum performance to approach the upper bound limit (2008). The membranes with PDMS-g-POEM exhibited greater CO2 permeability and CO2/N2 selectivity than those with a zeolitic imidazolate framework (ZIF-8), a well-known expensive inorganic filler, indicating the effectiveness of PDMS-g-POEM micelles for CO2 capture.© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.