2-Phenylpyridine
2-Phenylpyridine structure
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Common Name | 2-Phenylpyridine | ||
|---|---|---|---|---|
| CAS Number | 1008-89-5 | Molecular Weight | 155.196 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 270.8±9.0 °C at 760 mmHg | |
| Molecular Formula | C11H9N | Melting Point | -5°C | |
| MSDS | USA | Flash Point | 113.3±11.4 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Synthesis, characterization, photophysics and electrochemical study of luminescent iridium(III) complexes with isocyanoborate ligands.
Dalton Trans. 44 , 15135-44, (2015) A new series of cyclometalated iridium(III) complexes with isocyanoborate ligands [Ir(R2ppy)2(L)(CNBR'3)] (R = H or F; L = CNC6H4Cl-4 or PPh3; R' = Ph, C6F5 or C6H4Cl-4), [Ir(biqb)(ppy)(CNBR''3)] (R'' = C6F5 or C6H4Cl-4) and {Ir(ppy)2(CN)n[CNB(C6F5)3]2-n}(-) ... |
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Cyclometalated iridium(III) bipyridyl-phenylenediamine complexes with multicolor phosphorescence: synthesis, electrochemistry, photophysics, and intracellular nitric oxide sensing.
ChemMedChem 9(6) , 1316-29, (2014) We present a new class of phosphorescent cyclometalated iridium(III) bipyridyl-phenylenediamine complexes [Ir(N^C)2 (bpy-DA)](PF6 ) (bpy-DA=4-(N-(2-amino-5-methoxyphenyl)aminomethyl)-4'-methyl-2,2'-bipyridine; HN^C=2-(2,4-difluorophenyl)pyridine (Hdfppy) (1 a... |
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Direct, catalytic, and regioselective synthesis of 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles from N-oxides.
Org. Lett. 16(3) , 864-7, (2014) A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of copper catalysis and activation by lithium fluoride or magnesi... |
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Guest induced morphological transformation from nanospheres to nanowires by hydrogen bond self-assembly.
Dalton Trans. 42(14) , 4790-4, (2013) Phosphorescent nanospheres of a carboxyl-functionalized iridium complex ([Ir(ppy)2(Hdcbpy)], ppy: 2-phenylpyridine; Hdcbpy: 4-carboxy-2,2'-bipyridyl-4'-carboxylate) were prepared by a conventional precipitation method. Driven by hydrogen bond interaction betw... |
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Highly self-organized electron transfer from an iridium complex to p-benzoquinone due to formation of a pi-dimer radical anion complex triply bridged by scandium ions.
J. Am. Chem. Soc. 125(40) , 12090-1, (2003) Unusually high kinetic order was observed in self-organized Sc3+-promoted electron transfer from tris(2-phenylpyridine)iridium(III) [Ir(ppy)3] to p-benzoquinone (Q) in propionitrile, third-order with respect to the concentration of Sc3+ and second-order with ... |
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Coordination and bond activation in complexes of regioisomeric phenylpyridines with the nickel(II) chloride cation in the gas phase.
J. Phys. Chem. A 117(6) , 1171-80, (2013) Electrospray ionization of dilute solutions of phenylpyridines (phpy) in the presence of nickel(II) chloride leads to gaseous ions of the type [Ni(phpy)(m)](2+) with m = 3-5 and [NiCl(phpy)(n)](+) with n = 1-3, which are characterized by various gas-phase exp... |
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Improved high-brightness efficiency of phosphorescent organic LEDs comprising emitter molecules with small permanent dipole moments.
Adv. Mater. 22(29) , 3189-93, (2010)
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The synthesis and photophysics of tris-heteroleptic cyclometalated iridium complexes.
Dalton Trans. 40(38) , 9672-8, (2011) Herein we report the synthesis and photophysical study of tris-heteroleptic complexes of the general formula IrLL'(acac), where L and L' are two differently substituted 2-phenylpyridines (ppyH) and acacH is 2,4-pentanedione, using a combinatorial approach tha... |
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Tuning electronic structure and photophysical properties of [Ir(ppy)₂(py)₂]+ by substituents binding in pyridyl ligand: a computational study.
J. Mol. Model. 18(10) , 4615-24, (2012) Iridium (III) 2-phenylpyridine (ppy) complexes with two suitable monodentate L ligands [Ir(ppy)₂(L)₂]⁺ (ppy = 2-phenylpyridine, py = pyridine, L = 4-pyCN 1, 4-pyCHO 2, 4-pyCl 3, py 4, 4-pyNH₂ 5) were studied by density functional theory (DFT) and time-depende... |
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Hybridization vs. bond stretching isomerism in Ru(II) cyclometalated complexes of 2-phenylpyridine.
Molecules 17(1) , 34-47, (2011) The phenomenon of formation of two isomers, yellow and orange, of the cyclometalated Ru(II) complex, [Ru(o-C₆H₄-py)(MeCN)₄]⁺, was investigated by EELS spectroscopy and theoretical calculations. Both forms show very similar structures and spectroscopic propert... |