di-tert-butylmethylphosphine tetrafluor&
di-tert-butylmethylphosphine tetrafluor& structure
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Common Name | di-tert-butylmethylphosphine tetrafluor& | ||
|---|---|---|---|---|
| CAS Number | 870777-30-3 | Molecular Weight | 247.04100 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C9H21BF4P | Melting Point | >230ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS05 |
Signal Word | Danger | |
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Catalytic intermolecular direct arylation of perfluorobenzenes.
J. Am. Chem. Soc. 128 , 8754, (2006) Penta-, tetra-, tri-, and difluorobenzenes undergo direct arylation with a wide range of arylhalides in high yield. Inverse reactivity is observed compared to the common electrophilic aromatic substitution pathway since electron-deficient, C-H acidic arenes r... |
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Palladium-catalyzed direct arylation of nitro-substituted aromatics with aryl halides.
Org. Lett. 10 , 4533, (2008) Direct arylation reactions of nitrobenzenes and aryl halides occur in good yield and high ortho regioselectivity. These reactions can be performed on gram scale with as few as 3 equiv of the nitro arene relative to the aryl halide. The synthetic utility of th... |
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Palladium-catalyzed direct heck arylation of dual pi-deficient/pi-excessive heteroaromatics. Synthesis of C-5 arylated imidazo[1,5-a]pyrazines.
Org. Lett. 10 , 2923, (2008) A general and efficient synthesis of 5-aryl imidazo[1,5- a]pyrazines by palladium-catalyzed coupling of the corresponding 8-substituted derivatives with aryl halides is described. The scope of this new reaction for the imidazo[1,5- a]pyrazine ring system was ... |