Tetracyanoquinodimethane
Tetracyanoquinodimethane structure
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Common Name | Tetracyanoquinodimethane | ||
|---|---|---|---|---|
| CAS Number | 1518-16-7 | Molecular Weight | 204.187 | |
| Density | 1.4±0.1 g/cm3 | Boiling Point | 254.7±40.0 °C at 760 mmHg | |
| Molecular Formula | C12H4N4 | Melting Point | 287-289 °C (dec.)(lit.) | |
| MSDS | Chinese USA | Flash Point | 99.7±21.2 °C | |
| Symbol |
GHS06 |
Signal Word | Danger | |
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Novel organic solvents for electrochemistry at the liquid/liquid interface.
Analyst 140(6) , 1947-54, (2015) Two-phase voltammetry has been carried out using a reverse cell configuration, i.e. with the lower density organic solvent on the top of the aqueous solution in the cell, where the organic solvents contain either nitrile or ketone functional groups. The trans... |
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Charge-transfer crystallites as molecular electrical dopants.
Nat. Commun. 6 , 8560, (2015) Ground-state integer charge transfer is commonly regarded as the basic mechanism of molecular electrical doping in both, conjugated polymers and oligomers. Here, we demonstrate that fundamentally different processes can occur in the two types of organic semic... |
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Impact of Association Colloids on Lipid Oxidation in Triacylglycerols and Fatty Acid Ethyl Esters.
J. Agric. Food Chem. 63 , 10161-9, (2015) The impact of association colloids on lipid oxidation in triacylglycerols and fatty acid ethyl esters was investigated. Association colloids did not affect lipid oxidation of high oleic safflower and high linoleic safflower triacylglycerols, but were prooxida... |
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Solution-Processed Large-Area Nanocrystal Arrays of Metal-Organic Frameworks as Wearable, Ultrasensitive, Electronic Skin for Health Monitoring.
Small 11 , 3351-6, (2015) Pressure sensors based on solution-processed metal-organic frameworks nanowire arrays are fabricated with very low cost, flexibility, high sensitivity, and ease of integration into sensor arrays. Furthermore, the pressure sensors are suitable for monitoring a... |
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Spectrophotometric Determination of Distigmine Bromide, Cyclopentolate HCl, Diaveridine HCl and Tetrahydrozoline HCl via Charge Transfer Complex Formation with TCNQ and TCNE Reagents.
Iran. J. Pharm. Res. 14 , 701-14, (2015) The purpose of this investigation was directed to propose sensitive, accurate and reproducible methods of analysis that can be applied to determine distigmine bromide (DTB), cyclopentolate hydrochloride (CPHC), diaveridine hydrochloride (DVHC) and tetrahydroz... |
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Effects of methyl substituent on the charge-transfer complexations of dicarbazolylalkanes with p-chloranil, tetracyanoethylene and tetracyanoquinodimethane.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 79(5) , 1731-8, (2011) Series of 1,n-dicarbazolylalkanes and 1,n-di(3-methylcarbazolyl)alkanes (where n=1-5) were synthesized and the molar extinction coefficients, equilibrium constants, enthalpies, and entropies of their charge-transfer (CT) complexes with the π-acceptors p-chlor... |
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Molecular rotors of coronene in charge-transfer solids.
Chemistry 19(37) , 12313-24, (2013) Ten types of neutral charge transfer (CT) complexes of coronene (electron donor; D) were obtained with various electron acceptors (A). In addition to the reported 7,7,8,8-tetracyanoquinodimethane (TCNQ) complex of 1:1 stoichiometry with a DA-type alternating ... |
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A new colorimetric chemodosimeter for Hg2+ based on charge-transfer compound of N-methylpyrrole with TCNQ.
Talanta 83(2) , 644-50, (2010) Reaction of N-methylpyrrole and 7,7,8,8-tetracyanoquinodimethane (TCNQ) furnishes an intense blue unsymmetrical charge-transfer compound through regioselective attachment of tricyanoquinodimethane at the 2-position of N-methylpyrrole which was found to be sel... |
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Defect-Engineered Metal-Organic Frameworks.
Angew. Chem. Int. Ed. Engl. 54 , 7234-54, (2015) Defect engineering in metal-organic frameworks (MOFs) is an exciting concept for tailoring material properties, which opens up novel opportunities not only in sorption and catalysis, but also in controlling more challenging physical characteristics such as ba... |
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Spectrophotometric methods based on charge transfer complexation reactions for the determination of saxagliptin in bulk and pharmaceutical preparation.
Int. J. Biomed. Sci. 8 , 204-8, (2013) Simple, accurate and precise spectrophotometric methods have been developed for the determination of saxagliptin in bulk and dosage forms. The proposed methods are based on the charge transfer complexes of saxagliptin with 2,3-dichloro-5,6-dicyano-1,4-benzoqu... |