S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate
S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate structure
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Common Name | S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate | ||
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| CAS Number | 129946-88-9 | Molecular Weight | 402.332 | |
| Density | 7 g/cm3 | Boiling Point | N/A | |
| Molecular Formula | C14H8F6O3S2 | Melting Point | 155 °C | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Pd(II)-catalyzed ortho trifluoromethylation of arenes and insights into the coordination mode of acidic amide directing groups.
J. Am. Chem. Soc. 29th ed., 134 , 11948-11951, (2012) A Pd(II)-catalyzed trifluoromethylation of ortho C-H bonds with an array of N-arylbenzamides derived from benzoic acids is reported. N-Methylformamide has been identified as a crucial promoter of C-CF(3) bond formation from the Pd center. X-ray characterizati... |
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Copper-catalyzed trifluoromethylation of terminal alkynes using Umemoto's reagent Luo, D.-F.; et al.
Tetrahedron Lett. 22th ed., 53 , 2769-2772, (2012)
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Ionic liquids as new media for electrophilic trifluoromethylation reactions Pegot, B.; et al.
J. Fluor. Chem. 134 , 156-159, (2012)
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Copper-catalyzed trifluoromethylation of terminal alkenes through allylic C-H bond activation.
J. Am. Chem. Soc. 39th ed., 133 , 15300-15303, (2011) An unprecedented type of reaction for Cu-catalyzed trifluoromethylation of terminal alkenes is reported. This reaction represents a rare instance of catalytic trifluoromethylation through C(sp(3))-H activation. It also provides a mechanistically unique exampl... |