Tetrabutylammonium fluoride
Tetrabutylammonium fluoride structure
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Common Name | Tetrabutylammonium fluoride | ||
|---|---|---|---|---|
| CAS Number | 429-41-4 | Molecular Weight | 261.462 | |
| Density | 0.887 | Boiling Point | N/A | |
| Molecular Formula | C16H36FN | Melting Point | 62-63 °C(lit.) | |
| MSDS | Chinese | Flash Point | -17 ºC | |
| Symbol |
GHS05 |
Signal Word | Danger | |
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High-turnover hypoiodite catalysis for asymmetric synthesis of tocopherols.
Science 345(6194) , 291-4, (2014) The diverse biological activities of tocopherols and their analogs have inspired considerable interest in the development of routes for their efficient asymmetric synthesis. Here, we report that chiral ammonium hypoiodite salts catalyze highly chemo- and enan... |
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Tandem cyclization of α-cyano α-alkynyl aryl ketones induced by tert-butyl hydroperoxide and tetrabutylammonium iodide.
Org. Lett. 14(23) , 6024-7, (2012) The radical cascade protocol of the α-cyano α-TMS/aryl-capped alkynyl aryl ketones promoted by tert-butyl hydroperoxide under catalysis with tetrabutylammonium iodide in refluxing benzene has been developed, leading to the construction of a variety of highly ... |
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Design, Preparation, and Characterization of Zn and Cu Metallopeptides Based On Tetradentate Aminopyridine Ligands Showing Enhanced DNA Cleavage Activity.
Inorg. Chem. 54 , 10542-58, (2015) The conjugation of redox-active complexes that can function as chemical nucleases to cationic tetrapeptides is pursued in this work in order to explore the expected synergistic effect between these two elements in DNA oxidative cleavage. Coordination complexe... |
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The uptake of trehalose glycolipids by macrophages is independent of Mincle.
ChemBioChem. 16(4) , 683-93, (2015) Trehalose glycolipids play an important role in the pathogenesis of Mycobacterium tuberculosis and are used as adjuvants for vaccines; however, much still remains unanswered about the mechanisms through which these glycolipids exert their immunomodulatory pot... |
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A 7-Deazaadenosylaziridine Cofactor for Sequence-Specific Labeling of DNA by the DNA Cytosine-C5 Methyltransferase M.HhaI.
Molecules 20 , 20805-22, (2015) DNA methyltransferases (MTases) catalyze the transfer of the activated methyl group of the cofactor S-adenosyl-l-methionine (AdoMet or SAM) to the exocyclic amino groups of adenine or cytosine or the C5 ring atom of cytosine within specific DNA sequences. The... |
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Synthetic (+)-terrein suppresses interleukin-6/soluble interleukin-6 receptor induced-secretion of vascular endothelial growth factor in human gingival fibroblasts.
Bioorg. Med. Chem. 22(19) , 5338-44, (2014) Interleukin (IL)-6 is a proinflammatory cytokine that performs a wide variety of biological functions, including important roles in the progression of chronic inflammatory diseases such as periodontal disease. (+)-Terrein, a secondary bioactive fungal metabol... |
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Homogeneous detection of caspase-3 using intrinsic fluorescence resonance energy transfer (iFRET).
Biosens. Bioelectron. 67 , 413-8, (2015) Caspase-3 is an apoptotic cysteine protease and its aberrancy is highly implicated to numerous diseases thereby rendering caspase-3 activity as an important disease marker. Most caspase-3 sensors are caspase-3 substrates of which the fluorescence signals are ... |
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RNA editing in eag potassium channels: biophysical consequences of editing a conserved S6 residue.
Channels (Austin.) 6(6) , 443-52, (2012) RNA editing at four sites in eag, a Drosophila voltage-gated potassium channel, results in the substitution of amino acids into the final protein product that are not encoded by the genome. These sites and the editing alterations introduced are K467R (Site 1,... |
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Quantitative imaging of ion transport through single nanopores by high-resolution scanning electrochemical microscopy.
J. Am. Chem. Soc. 134(24) , 9856-9, (2012) Here we report on the unprecedentedly high resolution imaging of ion transport through single nanopores by scanning electrochemical microscopy (SECM). The quantitative SECM image of single nanopores allows for the determination of their structural properties,... |
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Photoinduced ligand exchange and DNA binding of cis-[Ru(phpy)(phen)(CH3CN)2]+ with long wavelength visible light.
J. Inorg. Biochem. 121 , 77-87, (2013) The complex cis-[Ru(phpy)(phen)(CH3CN)2](+) (phpy=2-phenylpyridine, phen=1,10-phenanthroline) was investigated as a potential photodynamic therapy (PDT) agent. This complex presents desirable photochemical characteristics including a low energy absorption tai... |