t-butyl nitrite
t-butyl nitrite structure
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Common Name | t-butyl nitrite | ||
|---|---|---|---|---|
| CAS Number | 540-80-7 | Molecular Weight | 103.120 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 63.5±9.0 °C at 760 mmHg | |
| Molecular Formula | C4H9NO2 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | -21.4±13.2 °C | |
| Symbol |
GHS02, GHS07 |
Signal Word | Danger | |
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The convenient preparation of stable aryl-coated zerovalent iron nanoparticles.
Beilstein J. Nanotechnol. 6 , 1192-8, (2015) A novel approach for the in situ synthesis of zerovalent aryl-coated iron nanoparticles (NPs) based on diazonium salt chemistry is proposed. Surface-modified zerovalent iron NPs (ZVI NPs) were prepared by simple chemical reduction of iron(III) chloride aqueou... |
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Gas-phase tyrosine-to-cysteine radical migration in model systems.
Eur. J. Mass Spectrom. (Chichester, Eng.) 21 , 589-97, (2015) Radical migration, both intramolecular and intermolecular, from the tyrosine phenoxyl radical Tyr(O(∙)) to the cysteine radical Cys(S(∙)) in model peptide systems was observed in the gas phase. Ion-molecule reactions (IMRs) between the radical cation of homot... |
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Chemoselective nitration of aromatic sulfonamides with tert-butyl nitrite.
Chem. Commun. (Camb.) 49(5) , 514-6, (2013) A methodology for the efficient conversion of aromatic sulfonamides into their mono-nitro derivatives using tert-butyl nitrite is reported. The reaction exhibits a high degree of chemoselectivity for sulfonamide functionalized aryl systems, even in the presen... |
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Efficient conversion of aromatic amines into azides: a one-pot synthesis of triazole linkages.
Org. Lett. 9 , 1809, (2007) [reaction: see text] An efficient and improved procedure for the preparation of aromatic azides and their application in the Cu(I)-catalyzed azide-alkyne 1,3-dipolar cycloaddition ("click reaction") is described. The synthesis of aromatic azides from the corr... |
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Visible light photocatalyzed direct conversion of aryl-/heteroarylamines to selenides at room temperature.
Org. Lett. 16(6) , 1814-7, (2014) A novel strategy for the direct conversion of aryl- and heteroarylamines to selenides has been developed via diazotization of amines with tert-butyl nitrite in neutral medium followed by reaction with diaryl/diheteroaryl/dialkyl diselenides in one pot under p... |
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Aerobic radical multifunctionalization of alkenes using tert-butyl nitrite and water.
Beilstein J. Org. Chem. 9 , 1713-7, (2013) Water induces a change in the product of radical multifunctionalization reactions of aliphatic alkenes involving an sp(3) C-H functionalization by an 1,5-hydrogen shift using tert-butyl nitrite and molecular oxygen. The reaction without water, reported previo... |
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tert-Butyl Nitrite. Liu Y.
Synlett 2011(08) , 1184-85, (2011)
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J. Org. Chem. 42 , 2426, (1977)
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J. Org. Chem. 42 , 2431, (1977)
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J. Org. Chem. 42 , 3494, (1977)
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