1-bromo-1-propene
1-bromo-1-propene structure
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Common Name | 1-bromo-1-propene | ||
|---|---|---|---|---|
| CAS Number | 590-15-8 | Molecular Weight | 120.97600 | |
| Density | 1.420 g/mL at 20 °C(lit.) | Boiling Point | 64-65 °C(lit.) | |
| Molecular Formula | C3H5Br | Melting Point | −116 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 5 °F | |
| Symbol |
GHS02, GHS07 |
Signal Word | Danger | |
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Palladium-catalyzed enantioselective alpha-arylation and alpha-vinylation of oxindoles facilitated by an axially chiral P-stereogenic ligand.
J. Am. Chem. Soc. 131(29) , 9900-1, (2009) The enantioselective alpha-arylation and alpha-vinylation of oxindoles catalyzed by Pd and a biarylmonophosphine ligand with both axial and phosphorus-based chirogenicity is reported. The resultant quaternary carbon stereocenters are formed in high enantiomer... |
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Preparation of (+)-trans-isoalliin and its isomers by chemical synthesis and RP-HPLC resolution.
J. Biomol. Tech. 25(3) , 67-76, (2014) Naturally occurring (+)-trans-isoalliin, (R(C)R(S))-(+)-trans-S-1-propenyl-L-cysteine sulfoxide, is a major cysteine sulfoxide in onion. The importance of producing it synthetically to support further research is very well recognized. The (+)-trans-isoalliin ... |
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Structure Analysis of Poly (propylene-β-d oxide) by Proton Nuclear Magnetic Resonance Spectroscopy. Oguni N, et al.
Macromolecules 6(3) , 459-465, (1973)
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cis-trans Isomerization of 1-Bromo-1-propene and Related Compounds. Harwell, KE and Hatch LF.
J. Am. Chem. Soc. 77(6) , 1682-1684, (1955)
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Substituted Dienols from Palladium Catalyzed Coupling of Hydroaluminated Enynols with Aryl Iodides. Crook KE, et al.
Lett. Org. Chem. 5(3) , 158-164, (2008)
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Facile synthesis of trans-S-1-propenyl-L-cysteine sulfoxide (isoalliin) in onions (Allium cepa). Lee S, et al.
Bull. Korean Chem. Soc. 32 , 319-320, (2011)
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Reductive cross-coupling of 3-substituted delta 3-cephems with alkenyl halides in an Al/PbBr2/NiBr2(bpy) triplemetal redox system. Synthesis of 3-alkenyl-delta 3-cephems.
J. Org. Chem. 66(2) , 570-7, (2001) Synthesis of 3-alkenyl-delta 3-cephems was performed successfully by cross-coupling 3-(trifluoromethylsulfonyloxy or chloro)-delta 3-cephem with alkenyl halides, e.g., vinyl bromide, trans-1-bromo-1-propene, and trans-beta-bromostyrene in an Al/cat.PbBr2/cat.... |
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The Preparation of Long Chain Alkylamine Hydrochlorides1a. Murr BL and Lester CT.
J. Am. Chem. Soc. 77(6) , 1684-1685, (1955)
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