Lithium bis(trimethylsilyl)amide
Lithium bis(trimethylsilyl)amide structure
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Common Name | Lithium bis(trimethylsilyl)amide | ||
|---|---|---|---|---|
| CAS Number | 4039-32-1 | Molecular Weight | 167.326 | |
| Density | 0.891 g/mL at 25 °C | Boiling Point | 55-56 °C | |
| Molecular Formula | C6H18LiNSi2 | Melting Point | 73°C | |
| MSDS | Chinese | Flash Point | 48 °F | |
| Symbol |
GHS02, GHS05 |
Signal Word | Danger | |
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Design, synthesis and biological evaluation of small molecules as potent glucosidase inhibitors.
Eur. J. Med. Chem. 100 , 188-96, (2015) Herein we have reported design, synthesis and in vitro biological evaluation of a library of bicyclic lactams that led to the discovery of compounds 6 and 7 as a novel class of α-glucosidase inhibitors. They inhibited α-glucosidase (yeast origin) in a mixed t... |
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Effect of concentration of trimethylchlorosilane (TMCS) and hexamethyldisilazane (HMDZ) silylating agents on surface free energy of silica aerogels.
J. Colloid. Interface Sci. 356(1) , 298-302, (2011) The surface free energy of a solid determines its surface and interfacial behavior in processes like wetting and adhesion which is crucial for silica aerogels in case of organic liquid absorption and transportation of chemicals at nano-scale for biotechnologi... |
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Independent Composition and Size Control for Highly Luminescent Indium-Rich Silver Indium Selenide Nanocrystals.
ACS Nano 9 , 11134-42, (2015) Ternary I-III-VI nanocrystals, such as silver indium selenide (AISe), are candidates to replace cadmium- and lead-based chalcogenide nanocrystals as efficient emitters in the visible and near IR, but, due to challenges in controlling the reactivities of the g... |
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A facile two-step dipping process based on two silica systems for a superhydrophobic surface.
Chem. Commun. (Camb.) 47(38) , 10761-3, (2011) A silica microsphere suspension and a silica sol are employed in a two-step dipping process for the preparation of a superhydrophobic surface. It's not only a facile way to achieve the lotus effect, but can also create a multi-functional surface with differen... |
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Trimethylsilylation of cellulose in ionic liquids.
Macromol. Biosci. 9(4) , 369-75, (2009) Trimethylsilylation of cellulose in different 1,3-dialkylimidazolium ionic liquids (IL) with hexamethyldisilazane (HMDS) as a silylating agent was investigated. Trimethylsilyl (TMSi) cellulose with a degree of substitution (DS) greater than 1 is insoluble in ... |
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Two-dimensional self-assemblies of silica nanoparticles formed using the "bubble deposition technique".
Langmuir 26(22) , 16828-32, (2010) Two-dimensional silica nanoparticle assemblies were obtained by deposition of bubble made from a surfactant solution containing nanoparticles onto hydrophobic silicon substrate. The morphologies of the nanoparticle assemblies can be finely controlled by sever... |
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Reactions of (-)-sparteine with alkali metal HMDS complexes: conventional meets the unconventional.
Chem. Commun. (Camb.) (39) , 5835-7, (2009) 'Conventional' (-)-sparteine adducts of lithium and sodium 1,1,1,3,3,3-hexamethyldisilazide (HMDS) were prepared and characterised, along with an unexpected and 'unconventional' hydroxyl-incorporated sodium sodiate, [(-)-sparteine x Na(mu-HMDS)Na x (-)-sparte... |
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Simultaneous analysis of basic, acidic and neutral compounds on an endcapped octadecylsilane silica-based monolith by pressure-assisted capillary electrochromatography.
Electrophoresis 29(4) , 944-51, (2008) This simultaneous separation of basic, acidic and neutral analytes by pressure-assisted CEC (pCEC) using a hybrid (tetramethoxysilane and methyltrimethoxysilane) silica-based monolith, chemically modified with octadecyldimethylchlorosilane followed by endcapp... |
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Nondestructively creating nanojunctions by combined-dynamic-mode dip-pen nanolithography.
ChemPhysChem 10(13) , 2226-9, (2009)
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Detecting cells on the surface of a silver electrode quartz crystal microbalance using plasma treatment and graft polymerization.
Colloids Surf. B Biointerfaces 73(2) , 244-9, (2009) This paper utilizes a silver electrode quartz crystal microbalance (QCM) mass sensor to detect the physiology of cells. This study also investigates the plasma surface modification of silver electrode QCMs through deposition of hexamethyldisilazane (HMDSZ) fi... |