Lithium perchlorate trihydrate
Lithium perchlorate trihydrate structure
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Common Name | Lithium perchlorate trihydrate | ||
|---|---|---|---|---|
| CAS Number | 13453-78-6 | Molecular Weight | 160.43700 | |
| Density | 1.841 g/mL at 25 °C(lit.) | Boiling Point | N/A | |
| Molecular Formula | ClH6LiO7 | Melting Point | 95 °C | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS03, GHS07 |
Signal Word | Danger | |
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Notable effects of the metal salts on the formation and decay reactions of α-tocopheroxyl radical in acetonitrile solution. The complex formation between α-tocopheroxyl and metal cations.
J. Phys. Chem. B 115(32) , 9880-8, (2011) The measurement of the UV-vis absorption spectrum of α-tocopheroxyl (α-Toc(•)) radical was performed by reacting aroxyl (ArO(•)) radical with α-tocopherol (α-TocH) in acetonitrile solution including four kinds of alkali and alkaline earth metal salts (MX or M... |
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Transformation of D-(-)-ribose into a natural product-like scaffold via a Lewis acid catalyzed intramolecular hetero-Diels-Alder reaction.
Nucleosides Nucleotides Nucleic Acids 26(6-7) , 701-4, (2007) Starting from D-(-)-ribose, a tricyclic natural product-like scaffold suitable for combinatorial derivatization was synthesized via an intramolecular hetero-Diels-Alder reaction. Lithium perchlorate was found to enhance the reaction rate and, at the same time... |
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Anion-induced reconstitution of a self-assembling system to express a chloride-binding Co10L15 pentagonal prism.
Nature Chemistry 4(9) , 751-6, (2012) Biochemical systems are adaptable, capable of reconstitution at all levels to achieve the functions associated with life. Synthetic chemical systems are more limited in their ability to reorganize to achieve new functions; they can reconfigure to bind an adde... |
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[An IR study of ion solvation and association of lithium perchlorate in some organic solvents].
Guang Pu Xue Yu Guang Pu Fen Xi 21(4) , 472-4, (2001) The infrared (IR) spectra of propylene carbonate (PC), gamma-butyrolactone (BL) and diethyl carbonate (DEC) in the presence of LiClO4 have been investigated. It is shown that the interactions between Li+ and these solvents occur on the oxygen atoms of the car... |
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Ion-molecule interactions in solutions of lithium perchlorate in propylene carbonate + diethyl carbonate mixtures: an IR and molecular orbital study.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 58(10) , 2097-104, (2002) FTIR spectra have been recorded and analyzed for solutions of lithium perchlorate in propylene carbonate (PC), diethyl carbonate (DEC), and PC + DEC mixtures. It has been shown that the carbonyl stretch bands for PC and DEC are very sensitive to the interacti... |
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Infrared (attenuated total reflection) study of propylene carbonate solutions containing lithium and sodium perchlorate.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 64(2) , 372-82, (2006) Attenuated total reflection infrared spectroscopy was used to examine the concentration dependent solvation of LiClO4 and NaClO4 electrolytes in propylene carbonate (PC). Factor analysis and curve fitting techniques were performed on the measured spectra and ... |
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Solvation of LiClO4 and NaClO4 in deuterated acetonitrile studied by means of infrared and Raman spectroscopy.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 58(8) , 1747-56, (2002) Vibrational characteristics of CD3CN solutions of LiClO4 and NaClO4 have been studied by means of infrared and Raman spectroscopy. Blue shifts of 22 and 11 cm(-1) of the v2 C[triple bond]N stretch are observed resulting from interaction of CD3CN with Li+ and ... |
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Improved surface-enhanced Raman scattering on electrochemically roughened silver substrates prepared in bielectrolyte solutions.
Anal. Chim. Acta 584(2) , 433-8, (2007) In this work, the effect of supplemental LiClO(4) electrolytes in KCl solutions used in roughening silver substrates by electrochemical triangular-wave oxidation-reduction cycles (ORC) on surface-enhanced Raman scattering (SERS) was first investigated. To pre... |
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Chemical reactivity predictions: use of data mining techniques for analyzing regioselective azidolysis of epoxides.
J. Comput. Chem. 31(14) , 2612-9, (2010) Azidolysis of epoxides followed by reduction of the intermediate azido alcohols constitutes a valuable synthetic tool for the construction of beta-amino alcohols, an important chemical functionality occurring in many biologically active compounds of natural o... |
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A unique molten globule state occurs during unfolding of cytochrome c by LiClO4 near physiological pH and temperature: structural and thermodynamic characterization.
Biochemistry 45(14) , 4695-702, (2006) We have carried out denaturation studies of bovine cytochrome c (cyt c) by LiClO4 at pH 6.0 and 25 degrees C by observing changes in difference molar absorbance at 400 nm (Deltaepsilon400), mean residue ellipticities at 222 nm ([theta]222) and difference mean... |