Cupric fluoride

Cupric fluoride Structure
Cupric fluoride structure
Common Name Cupric fluoride
CAS Number 7789-19-7 Molecular Weight 101.54300
Density 4.23 Boiling Point 950ºC
Molecular Formula CuF2 Melting Point 950ºC
MSDS Chinese USA Flash Point N/A
Symbol GHS05
GHS05
Signal Word Danger

Catalytic enantioselective aldol reaction to ketones.

J. Am. Chem. Soc. 128 , 7164, (2006)

An enantioselective aldol reaction between ketones and ketene silyl acetals is described using CuF-chiral phosphine as a catalyst. The key for high enantioselectivity was the development of a novel ligand derived from Taniaphos combined with the unique accele...

Nucleophilic activation of alkenyl and aryl boronates by a chiral Cu(I)F complex: catalytic enantioselective alkenylation and arylation of aldehydes.

Chem. Asian J. 1(1-2) , 161-6, (2006)

A new method for the catalytic enantioselective alkenylation and arylation of aldehydes involves the activation of alkenyl and aryl boronates by a catalytic amount of the Cu(I)F-DTBM-segphos complex through transmetalation, generating novel alkenyl and aryl c...

The effect of various fluoride compounds on the development of experimental root surface caries in hamsters.

Bull. Tokyo Med. Dent. Univ. 42(3) , 105-16, (1995)

The aim of this investigation was to evaluate the effect of topical applications of various fluoride compounds on the development of root surface caries in hamsters. Male golden hamsters (n = 115) were divided into 7 groups and were given a caries-promoting d...

[Effect of fluoride of copper and iron on polymerization of MMA/TBBO resin and adhesion to dentin].

Shika Zairyo. Kikai 8(3) , 425-30, (1989)

As a model experiment to understand the mechanism of adhesion of the MMA/TBBO resin to dentin, polymerization of MMA/TBBO was investigated in the presence of a collagen sheet treated with the aqueous citric acid (CA) solutions of copper fluoride (CF), ferric ...

[Study on adhesion mechanism of MMA-TBBO resin to dentin. A model experiment using decalcified dentin].

Shika Zairyo. Kikai 9(2) , 320-5, (1990)

As a model experiment to understand the mechanism of adhesion of the MMA-TBBO resin to dentin, MMA-TBBO was polymerized using a decalcified dentin sheet treated with aqueous citric acid (CA) solutions of copper fluoride (CF), ferric fluoride (FF), or ferric c...

Effect of copper fluoride and copper sulfate on dental plaque, Streptococcus mutans and caries in hamsters.

Scand. J. Dent. Res. 96(5) , 390-2, (1988)

Topical applications of 10 mM CuF2, 10 mM CuSO4, or 20 mM NaF solutions were performed twice a day in hamsters infected with S. mutans and maintained on a high sucrose diet. Animals receiving the copper compounds exhibited lower plaque scores than control ani...

Asymmetric trifluoromethylation of aromatic aldehydes by cooperative catalysis with (IPr)CuF and quinidine-derived quaternary ammonium salt.

Org. Biomol. Chem. 10(47) , 9334-7, (2012)

A general enantioselective trifluoromethylation of aldehydes has been developed using (IPr)CuF and quinidine-derived quaternary ammonium salt as the cooperative catalyst. Thus, a wide range of aromatic aldehydes have been converted to the corresponding produc...

"A greener" synthetic route for fluoroaromatics via copper (II) fluoride. Subramanian MA and Manzer LE

Science 297(5587) , 1665-1665, (2002)

Magnetic and crystal structure of copper(II) fluoride Fischer P, et al.

J. Phys. Chem. Solids 35(12) , 1683-1689, (1974)