3-苄氧基-1-丙醇
3-苄氧基-1-丙醇结构式
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常用名 | 3-苄氧基-1-丙醇 | 英文名 | 3-Benzyloxy-propan-1-ol |
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| CAS号 | 4799-68-2 | 分子量 | 166.217 | |
| 密度 | 1.0±0.1 g/cm3 | 沸点 | 274.3±0.0 °C at 760 mmHg | |
| 分子式 | C10H14O2 | 熔点 | 38ºC | |
| MSDS | 中文版 美版 | 闪点 | 126.9±14.6 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Selective catalytic sp3 C-O bond cleavage with C-N bond formation in 3-alkoxy-1-propanols.
Org. Lett. 14(12) , 2992-5, (2012) The ruthenium catalyzed selective sp(3) C-O cleavage with amide formation was reported in reactions of 3-alkoxy-1-propanol derivatives and amines. The cleavage only occurs at the C3-O position even with 3-benzyloxy-1-propanol. Based on the experimental result... |
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Total synthesis of (+)-cocaine via desymmetrization of a meso-dialdehyde.
Org. Lett. 6(19) , 3305-8, (2004) [reaction: see text] The total synthesis of (+)-cocaine is described. An extension of the recently reported proline catalyzed intramolecular enol-exo-aldol reaction to a meso-dialdehyde provided the tropane ring skeleton directly with good enantiomeric excess... |
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Synthesis of galactosyl phosphate diester derivatives of nucleosides.
Carbohydr. Res. 257(2) , 323-30, (1994)
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Asymmetric synthesis of (R)-and (S)-4-methyloctanoic acids. A new route to chiral fatty acids with remote stereocenters. Muñoz L, et al.
Tetrahedron Asymmetry 20(4) , 420-424, (2009)
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