六氟磷酸四乙氰铜四氟硼酸盐
六氟磷酸四乙氰铜四氟硼酸盐结构式
|
常用名 | 六氟磷酸四乙氰铜四氟硼酸盐 | 英文名 | Copper(1+) tetrafluoroborate acetonitrile (1:1:4) |
|---|---|---|---|---|
| CAS号 | 15418-29-8 | 分子量 | 314.558 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C8H12BCuF4N4 | 熔点 | 164 °C(dec.) | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS05 |
信号词 | Danger |
|
Enantioselective aziridination using copper complexes of biaryl Schiff bases.
J. Org. Chem. 67 , 3450, (2002) Racemic 2,2'-diamino-6,6'-dimethylbiphenyl is resolved using simulated moving bed chromatography, and the absolute configuration of the enantiomers is confirmed via the X-ray crystal structure of a derivative. The diamine is condensed with a range of aldehyde... |
|
|
Catalytic enantioselective synthesis of quaternary all-carbon stereogenic centers. Preparation of alpha,alpha'-disubstituted beta,gamma-unsaturated esters through Cu-catalyzed asymmetric allylic alkylations.
Org. Lett. 7 , 1255, (2005) [reaction: see text] Peptide-based chiral ligands, readily prepared from commercially available materials, are used to promote Cu-catalyzed asymmetric allylic alkylations of alpha,beta-unsaturated esters bearing a gamma-phosphate with various alkylzinc reagen... |
|
|
Stoichiometry and cluster specificity of copper binding to metallothionein: homogeneous metal clusters.
Biochem. J. 317 ( Pt 2) , 395-402, (1996) Experiments were done to define the stoichiometry of binding of Cu(I) to metallothionein (MT) and to determine its sites of binding in mixed-metal species. Spectrophotometric titrations of rabbit liver Cd7-MT 2, apoMT, and Cd4-alpha-domain with Cu(I) revealed... |
|
|
Moore, J. A.; Partain, E. M.
J. Org. Chem. 48 , 1105, (1983)
|
|
|
Bethell, D.; Jenkins, I. L.; Quan, P. M.
J. Chem. Soc., Perkin Trans. II , 1789, (1985)
|
|
|
Paryzek, Z.; Martynow, J.
J. Chem. Soc. Perkin Trans. I , 599, (1990)
|
|
|
Le Bras, J.; Muzart, J.
Tetrahedron Lett. 43 , 431, (2002)
|