2-甲氧基环己酮
2-甲氧基环己酮结构式
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常用名 | 2-甲氧基环己酮 | 英文名 | 2-Methoxycyclohexanone |
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| CAS号 | 7429-44-9 | 分子量 | 128.16900 | |
| 密度 | 1.02 g/mL at 25 °C(lit.) | 沸点 | 185 °C750 mm Hg(lit.) | |
| 分子式 | C7H12O2 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 157 °F |
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Palladium(II)-catalyzed oxidation of aldehydes and ketones. 1. Carbonylation of ketones with carbon monoxide catalyzed by palladium(II) chloride in methanol.
J. Org. Chem. 66(1) , 180-5, (2001) Unsubstituted or alkyl-substituted cyclic ketones react with PdCl2 in methanol under a CO atmosphere to give mainly acyclic diesters along with some acyclic chloro-substituted monoesters. The monosubstituted cyclic ketones, 2-hydroxy- and 2-methoxycyclohexano... |
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Infrared spectroscopy and theoretical calculations as tools for the conformational analysis of 2-methoxycyclohexanone.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 59(6) , 1177-82, (2003) The conformational equilibrium of 2-methoxycyclohexanone has been analyzed through infrared spectroscopy and theoretical calculations. These calculations indicate that six conformations may be present in the vapor phase, due to the rotation of the methoxy gro... |
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