2-Methoxycyclohexanone
2-Methoxycyclohexanone structure
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Common Name | 2-Methoxycyclohexanone | ||
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| CAS Number | 7429-44-9 | Molecular Weight | 128.16900 | |
| Density | 1.02 g/mL at 25 °C(lit.) | Boiling Point | 185 °C750 mm Hg(lit.) | |
| Molecular Formula | C7H12O2 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 157 °F | |
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Palladium(II)-catalyzed oxidation of aldehydes and ketones. 1. Carbonylation of ketones with carbon monoxide catalyzed by palladium(II) chloride in methanol.
J. Org. Chem. 66(1) , 180-5, (2001) Unsubstituted or alkyl-substituted cyclic ketones react with PdCl2 in methanol under a CO atmosphere to give mainly acyclic diesters along with some acyclic chloro-substituted monoesters. The monosubstituted cyclic ketones, 2-hydroxy- and 2-methoxycyclohexano... |
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Infrared spectroscopy and theoretical calculations as tools for the conformational analysis of 2-methoxycyclohexanone.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 59(6) , 1177-82, (2003) The conformational equilibrium of 2-methoxycyclohexanone has been analyzed through infrared spectroscopy and theoretical calculations. These calculations indicate that six conformations may be present in the vapor phase, due to the rotation of the methoxy gro... |
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