2-甲基苯硼酸
2-甲基苯硼酸结构式
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常用名 | 2-甲基苯硼酸 | 英文名 | tolylboronic acid |
|---|---|---|---|---|
| CAS号 | 16419-60-6 | 分子量 | 135.96 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 283.4±33.0 °C at 760 mmHg | |
| 分子式 | C7H9BO2 | 熔点 | 162-164 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 125.2±25.4 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Ruthenium(0)-catalyzed sp3 C-H bond arylation of benzylic amines using arylboronates.
Org. Lett. 7th ed., 14 , 1930-1933, (2012) A Ru-catalyzed direct arylation of benzylic sp(3) carbons of acyclic amines with arylboronates is reported. This highly regioselective and efficient transformation can be performed with various combinations of N-(2-pyridyl) substituted benzylamines and arylbo... |
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Design and synthesis of active site inhibitors of the human farnesyl pyrophosphate synthase: apoptosis and inhibition of ERK phosphorylation in multiple myeloma cells.
J. Med. Chem. 7th ed., 55 , 3201-3215, (2012) Human farnesyl pyrophosphate synthase (hFPPS) controls intracellular levels of FPP and post-translational prenylation of small GTPase proteins, which are essential for cell signaling and cell proliferation. Clinical investigations provide evidence that N-BP i... |
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Efficient chiral monophosphorus ligands for asymmetric Suzuki-Miyaura coupling reactions.
Org. Lett. 9th ed., 14 , 2258-2261, (2012) A series of novel P-chiral monophosphorus ligands exhibit efficiency in asymmetric Suzuki-Miyaura coupling reactions, enabling the construction of an array of chiral biaryl products in high yields and excellent enantioselectivities (up to 96% ee) under mild c... |
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Phosphine-free Suzuki-Miyaura cross-coupling in aqueous media enables access to 2-C-aryl-glycosides.
Org. Lett. 7th ed., 14 , 1728-1731, (2012) A general strategy for the synthesis of 2-aryl-glycals and their elaboration to 2-C-aryl-α-glycosides and 1,5-anhydro-2-C-aryl-2-deoxy alditols are described. The use of reliable, efficient phosphine-free Suzuki-Miyaura cross-coupling of 2-iodoglycals in aque... |
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Pd-catalyzed direct arylation of phenylpyrazole: Synthesis of fipronil derivatives with aryl boronic acids promoted by a stoichiometric amount of NIS Zhang, X-H.; Han, J-S.; Zhong, P.
J. Fluor. Chem. 137 , 44-49, (2012)
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Ligand-free copper-catalyzed coupling of nitroarenes with arylboronic acids Zhang, J.; et al.
Green Chem. 4th ed., 14 , 912-916, (2012)
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Highly effective synthesis of C-5-substituted 2'-deoxyuridine using Suzuki-Miyaura cross-coupling in water Sartori, G.; et al.
Synthesis 5th ed., 44 , 767-772, (2012)
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Palladium nanoparticles immobilized by click ionic copolymers: Efficient and recyclable catalysts for Suzuki-Miyaura cross-coupling reaction in water Zhang, D.; Zhou, C.; Wang, R.
Catal. Commun. 22 , 83-88, (2012)
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Tetrahedron 63 , 6996, (2007)
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Glycerol as a recyclable solvent for copper-catalyzed cross-coupling reactions of diaryl diselenides with aryl boronic acids Ricordi, V. G.; et al.
Green Chem. 4th ed., 14 , 1030-1034, (2012)
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