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邻氟苯乙酮

邻氟苯乙酮结构式
邻氟苯乙酮结构式
品牌特惠专场
常用名 邻氟苯乙酮 英文名 1-(2-Fluorophenyl)ethanone
CAS号 445-27-2 分子量 138.14
密度 1.1±0.1 g/cm3 沸点 180.8±0.0 °C at 760 mmHg
分子式 C8H7FO 熔点 26-27ºC
MSDS 中文版 美版 闪点 61.7±0.0 °C
符号 GHS07
GHS07
信号词 Warning

Total synthesis of ascididemin via anionic cascade ring closure.

Chem. Commun. (Camb.) 48(72) , 9092-4, (2012)

A new and convergent synthesis of ascididemin is presented. Using an anionic cascade ring closure as the key step, this natural product is obtained in 45% overall yield in just 6 steps starting from 2'-fluoroacetophenone. This new approach was extended to the...

The enantioselective reduction of 2'-fluoroacetophenone utilizing a simplified CBS-reduction procedure. Garrett CE, et al.

Tetrahedron Asymmetry 13(13) , 1347-49, (2002)